Journal of Organometallic Chemistry p. 133 - 142 (1994)
Update date:2022-08-17
Topics:
Brefort, J.L.
Corriu, R.J.P.
Guerin, C.
Henner, B.J.L.
The pyrolysis of poly<(germylene)diacetylenes> and poly<a carbon sp2 matrix with disubstituted organogermyl and/or silyl groups.The ceramic residues contained a high amount of carbon (40-61percent) and all the germanium was recovered as metallic germanium above 500 deg C.Pyrolysis of poly<(germylene)diacetylenes> under ammonia gave germanium nitride after cross-linking and nitridation between 400 and 600 deg C. Key words: Germanium; Polymer; Diyne; Ceramic
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