Journal of Molecular Structure p. 133 - 140 (1992)
Update date:2022-08-28
Topics:
Kosmidis, C.
Boulakis, G.
Bolovinos, A.
Tsekeris, P.
Brint, P.
The two-photon resonance three photon ionization spectra of cyclopentanone, cyclohexanone and cycloheptanone in the region of the 3p Rydberg state have been recorded, analysed and compared with the one-photon absorption spectra.A new 3p origin is identified for cyclopentanone.The absence from the MPI spectra of a sharp spectral feature that is observed in the absorption spectra is discussed.Photochemical generation of acetaldehyde is observed at high laser intensities and possible mechanisms for this are considered.
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