Journal of Organometallic Chemistry p. 39 - 44 (1994)
Update date:2022-08-11
Topics:
Xie, Shaofeng
Georgiev, Emil M.
Roundhill, D. Max
Troev, Koljo
The hydrogenolysis of carbon tetrachloride to chloroform, and of trichlorofluoromethane to hydrodichlorofluoromethane, are catalyzed by the complexes RuCl2(PPh3)3 and RuCl2(dppe)2.The conversion of carbon tetrachloride into chloroform is more complete than the conversion of trichlorofluoromethane into hydrodichlorofluoromethane.Key words: Ruthenium; Hydrogenolysis; Carbon-chlorine bonds; Homogeneous catalysis
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