Hydrogenolysis of carbon-chlorine bonds in carbon tetrachloride and trichlorofluoromethane in the presence of catalytic quantities of tris(triphenylphosphine) ruthenium(II) dichloride

DOI: 10.1016/0022-328X(94)88181-2

Source and publish data:

Journal of Organometallic Chemistry p. 39 - 44 (1994)

Update date:2022-08-11

Topics:

Authors:

Xie, Shaofeng

Georgiev, Emil M.

Roundhill, D. Max

Troev, Koljo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(94)88181-2

The hydrogenolysis of carbon tetrachloride to chloroform, and of trichlorofluoromethane to hydrodichlorofluoromethane, are catalyzed by the complexes RuCl2(PPh3)3 and RuCl2(dppe)2.The conversion of carbon tetrachloride into chloroform is more complete than the conversion of trichlorofluoromethane into hydrodichlorofluoromethane.Key words: Ruthenium; Hydrogenolysis; Carbon-chlorine bonds; Homogeneous catalysis

Full text of DOI:10.1016/0022-328X(94)88181-2

Products guided by the article

Product name:Dichloromonofluoromethane

Cas No:75-43-4

R&D Labs maybe for 75-43-4

Zhejiang Hoshine Silicon Industry Co., Ltd.

Contact:86-573-89179966

Address:Zhapu Town, Pinghu City, Zhejiang, China
Shandong Loyal Chemical industrial Co.,Ltd

Contact:0533-7451788

Address:Linzi Chemical Industrial Park, Zibo, Shandong Province
Fujian Huitian Biological Pharmacy Co., Ltd.

Contact:0086-598-8300831; 8339920

Address:No.46,Taijiang Road,Sanming City,Fujian,China
Shanghai Kefu Chemical Co.,Ltd.

Contact:+86-21-34616196

Address:Room601-602, Xuhui Business Building, No.168, Yude Road, Shanghai
Zhejiang Chemicals Import & Export Corporation (ZHECHEM)

Contact:+86-571-87046953

Address:No. 37, Qingchun Road

Relevant to this article

Discovery of GluN2A-Selective NMDA Receptor Positive Allosteric Modulators (PAMs): Tuning Deactivation Kinetics via Structure-Based Design

Doi:10.1021/acs.jmedchem.5b02010
(2016)
Doi:10.1021/jo00924a010
(1974)
Electrochemically induced chain transformation of salicylaldehydes and alkyl cyanoacetates into substituted 4H-chromenes

Doi:10.1016/j.tetlet.2006.08.053
(2006)
X-ray and DFT studies of the structure and spectral property of 2-[2-(4-dimethylaminophenyl)ethenyl]-1-methyl-pyridinium iodide

Doi:10.1016/j.molstruc.2007.09.003
(2008)
Inhibition of the hydrogenation of tetralin by nitrogen and sulfur compounds over Ir/SBA-16

Doi:10.1016/j.apcata.2011.07.003
(2011)
Metal-Free Regioselective Cross Dehydrogenative Coupling of Cyclic Ethers and Aryl Carbonyls

Doi:10.1021/acs.joc.8b03048
(2019)

Article Doi