Hydrogenolysis of carbon-chlorine bonds in carbon tetrachloride and trichlorofluoromethane in the presence of catalytic quantities of tris(triphenylphosphine) ruthenium(II) dichloride

DOI: 10.1016/0022-328X(94)88181-2

Source and publish data:

Journal of Organometallic Chemistry p. 39 - 44 (1994)

Update date:2022-08-11

Topics:

Authors:

Xie, Shaofeng

Georgiev, Emil M.

Roundhill, D. Max

Troev, Koljo

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Article abstract of DOI:10.1016/0022-328X(94)88181-2

The hydrogenolysis of carbon tetrachloride to chloroform, and of trichlorofluoromethane to hydrodichlorofluoromethane, are catalyzed by the complexes RuCl2(PPh3)3 and RuCl2(dppe)2.The conversion of carbon tetrachloride into chloroform is more complete than the conversion of trichlorofluoromethane into hydrodichlorofluoromethane.Key words: Ruthenium; Hydrogenolysis; Carbon-chlorine bonds; Homogeneous catalysis

Full text of DOI:10.1016/0022-328X(94)88181-2

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