Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 1303 - 1310 (1985)
Update date:2022-08-11
Topics:
Pasteris, L.
Staricco, E. H.
Evidence is presented that rate measurements over a wide temperature range, 298-648 K, for the reaction of CF3 radicals with methyl cyanide show non-Arrhenius behaviour when the photolysis of trifluoromethyl iodide is used as a source radicals.The results presented here support the fact that the curved Arrhenius plot may be explained in terms of two reaction channels giving the same product, CF3H.One is the abstraction by the CF3 radicals and the other involves the iodine atom produced in the photolysis of CF3I.In order to obtain further information on the reaction mechanism the kinetic isotope effect has also been studied.
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