Tetrahedron Letters p. 3215 - 3218 (1985)
Update date:2022-08-11
Topics:
Matsuda, Isamu
Sato, Susumu
Hattori, Motoaki
Izumi, Yusuke
The isomerization of an α-trimethylsilyl ketone is lead to the corresponding trimethylsilyl enol ether with the enhanced regioselectivity by heating or by the assist of trimethylsilyl trifluoromethanesulfonate.The thermal reaction discloses a new regiodefined (E)-selective route to silyl enol ethers.
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