Journal of Organometallic Chemistry p. C27 - C29 (1987)
Update date:2022-08-11
Topics:
Pons, P.
Biran, C.
Bordeau, M.
Dunogues, J.
Sibille, S.
Perichon, J.
In a single compartment cell fitted with a sacrificial magnesium anode, electrochemical reduction of phenyl and benzyl halides in the presence of trimethylchlorosilane gave the corresponding phenyl- and benzyl-silanes in satisfactory yields.Under well chosen conditions, the synthesis of phenyltrimethylsilane from phenyl bromide or chloride was also found possible.
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