Journal of Physical Chemistry p. 13059 - 13061 (1995)
Update date:2022-08-16
Topics:
Hanson, D. R.
The reactive uptake of ClONO2 onto 18O-labeled ice and onto organic liquids was measured in a cylindrical flow tube reactor using chemical ionization detection.The hydrolysis of ClONO2 on H2(18)O ice produced primarily H(18)OCl, indicating that the Cl-ONO2 bond is broken upon hydrolysis on ice.The loss of ClONO2 onto liquid organic surfaces (ethylene glycol, cyclohexanone, decanol, and tridecane) was found to be efficient (reaction probability > 0.06), and the product HNO3 was detected in the gas phase.This suggests that dissociation or ionization are not prerequisites for heterogeneous reactions of ClONO2.
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