Tetrahedron Letters p. 45 - 46 (1980)
Update date:2022-08-16
Topics:
Lischewski, M.
Adam, G.
UV-irradiation of the aldehyde 1 leads to the 7-epimeric cyclobutanols 2a and 2b which undergo upon treatment with NaOCH3 retroaldol-like cleavage to 1 and 3.Oxidation and deacetylation of 3 affords the 16,17-dihydro-Δ15-gibberellin-A3 (5).
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(1981)
