PHOTOCYCLISIERUNG EINES GIBBERELLINALDEHYDS ZU EPIMEREN CYCLOBUTANOLEN UND DEREN BASISCHE RUECKSPALTUNG, PARTIALSYNTHESE VON 16,17-DIHYDRO-Δ15-GIBBERELLIN-A3

DOI: 10.1016/S0040-4039(00)93620-7

Source and publish data:

Tetrahedron Letters p. 45 - 46 (1980)

Update date:2022-08-16

Topics:

Authors:

Lischewski, M.

Adam, G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)93620-7

UV-irradiation of the aldehyde 1 leads to the 7-epimeric cyclobutanols 2a and 2b which undergo upon treatment with NaOCH3 retroaldol-like cleavage to 1 and 3.Oxidation and deacetylation of 3 affords the 16,17-dihydro-Δ₁₅-gibberellin-A³ (5).

Full text of DOI:10.1016/S0040-4039(00)93620-7

Products guided by the article

Product name:Gibberellic acid

Cas No:77-06-5

R&D Labs maybe for 77-06-5

Wuhan Kemi-Works Chemical Co., Ltd

website:http://www.kemiworks.com

Contact:86-27-85736489

Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China
TLS PHARMACEUTICAL CO.,LTD

Contact:0833-5590788/5590338/5590055

Address:Victory in the town of Red Star Village,Mount Emei City,industrial concentration area storage processing logistics parkpark
Shanghai better-in Medical Technology Co.,LTD.

Contact:+86-21-38921049

Address:Lane 720 zhangjianggaoke cailun road, Pudong, Shanghai, room 513
SHANGHAI ARCADIA BIOTECHNOLOGY LTD.

Contact:+86-21-61353236

Address:SUITE 901, BUILDING WENSLI, 1378 LU JIA BANG RD, SHANGAHI 200011, P.R.CHINA
Wuhan Shengmao Corp

website:http://www.shengmaochem.com

Contact:86-27-82853423, 82819281

Address:Rm 202, A Unit Huaqiao Building No. 2, Lihuangpi Road, Wuhan, China

Relevant to this article

Pd-Catalyzed Surface Reactions of Importance in Radiation Induced Dissolution of Spent Nuclear Fuel Involving H2

Doi:10.1002/cctc.201901128
(2019)
Kinetic studies of the Hydrolysis of Diketene Catalyzed by the Chloropalladium(II) Complex

Doi:10.1246/bcsj.57.1217
(1984)
Thiabendazole-based Rh(III) and Ir(III) biscyclometallated complexes with mitochondria-targeted anticancer activity and metal-sensitive photodynamic activity

Doi:10.1016/j.ejmech.2018.07.065
(2018)
Catalytic enantioselective epoxidation of alkenes with a tropinone-derived chiral ketone

Doi:10.1039/a708695d
(1998)
Synthesis of 4-substituted azopyridine-functionalized Ni(II)-porphyrins as molecular spin switches

Doi:10.3762/BJOC.16.210
(2020)
USE OF LIME SLURRIES FOR SAPONIFYING CARBOMETHOXYSULFATHIAZOLE IN THE MANUFACTURE OF SULFATHIAZOLE

Doi:10.1007/BF00759478
(1981)

Article Doi