Journal of Structural Chemistry p. 846 - 849 (1987)
Update date:2022-08-24
Topics:
Mamaeva, G. I.
Romanov, G. V.
Spiridonov, V. P.
Troyanov, S. I.
A method for the electron-diffraction investigation of unstable halides of transition elements with lower valences is described.The relative pressures of TiCl4, TiCl3, TiCl2, and TiCl vapors in the TiCl4 + Ti system at 400-2000 deg K were calculated.Electron-diffraction patterns of gaseous TiCl3 at 1100 deg K were obtained.The effective geometrical and vibrational parameters of the TiCl3 molecule were determined.The equilibrium structure with D3h symmetry was found within the harmonic approximation, and the vibrational frequencies and force constants were evaluated.
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