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Crystal Growth & Design
thermal stability (up to 270 °C) and a relatively large
bandgap of 2.82 eV. Moreover, Rb Sn Cl Br shows a
phaseꢀmatchable powder SHG response of 0.5 times of
KDP. The discovery of Rb Sn Cl Br would provide a
representative example of the research between strucꢀ
ture and properties and it is beneficial for further exploꢀ
ration of nonlinear optical materials among the Snꢀbased
halides.
(9) Liu, T.; Qin, J.; Zhang, G.; Zhu, T.; Niu, F.; Wu, Y.; Chen, C.
Mercury Bromide (HgBr ): A promising nonlinear optical mateꢀ
rial in IR region with a high laser damage threshold. Appl. Phys.
1
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6
7
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9
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8
2
Lett. 2008, 93 (9), 091102.
4
3
2
8
(
3
10) Zhang, G.; Liu, T.; Zhu, T.; Qin, J.; Wu, Y.; Chen, C. SbF :
A new secondꢀorder nonlinear optical material. Opt. Mater.
2008, 31 (1), 110ꢀ113.
(
11) Choi, M. H.; Kim, S. H.; Chang, H. Y.; Halasyamani, P. S.;
Ok, K. M. New Noncentrosymmetric Material ꢀ N(CH ZnCl
Tetrahedra. Inorg. Chem. 2009,
3
)
4
3
:
Polar Chains of Aligned ZnCl
48 (17), 8376ꢀ8382.
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ASSOCIATED CONTENT
(12) Tong, Y. Z.; Meng, X. Y.; Wang, Z. Z.; Chen, C. T.; Lee, M.
H. The mechanism of linear and nonlinear optical effects in
fluoride crystals. J. Appl. Phys. 2005, 98 (3), 033504.
Supporting Information.
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The Supporting Information is available free of charge on
files and additional data.
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13) Ren, P.; Qin, J. G.; Chen, C. T. A novel nonlinear optical
crystal for the IR region: Noncentrosymmetrically crystalline
4 3 2 8
Deposition CCDC number 1575046 for Rb Sn Cl Br .
CsCdBr3 and its properties. Inorg. Chem. 2003, 42 (1), 8ꢀ10.
(
14) Thirumal, K.; Chong, W. K.; Xie, W.; Ganguly, R.; Muduli,
AUTHOR INFORMATION
Corresponding Author
S. K.; Sherburne, M.; Asta, M.; Mhaisalkar, S.; Sum, T. C.; Soo,
H. S.; Mathews, N. MorphologyꢀIndependent Stable Whiteꢀ
Light Emission from SelfꢀAssembled TwoꢀDimensional Perovꢀ
skites Driven by Strong Exciton–Phonon Coupling to the Orꢀ
ganic Framework. Chem. Mater. 2017, 29 (9), 3947ꢀ3953.
(15) Xing, G.; Mathews, N.; Sun, S.; Lim, S. S.; Lam, Y. M.;
Graetzel, M.; Mhaisalkar, S.; Sum, T. C. LongꢀRange Balanced
Electronꢀ and HoleꢀTransport Lengths in OrganicꢀInorganic
*
zslin@mail.ipc.ac.cn.
Author Contributions.
All authors have given approval to the final version of the
manuscript
Notes
CH
3 3 3
NH PbI . Science 2013, 342 (6156), 344ꢀ347.
(
16) Zhu, H.; Fu, Y.; Meng, F.; Wu, X.; Gong, Z.; Ding, Q.; Gusꢀ
The authors declare no competing financial interests.
tafsson, M. V.; Trinh, M. T.; Jin, S.; Zhu, X. Y. Lead halide perꢀ
ovskite nanowire lasers with low lasing thresholds and high
quality factors. Nat. Mater. 2015, 14 (6), 636ꢀU115.
(17) Weidman, M. C.; Goodman, A. J.; Tisdale, W. A. Colloidal
Halide Perovskite Nanoplatelets: An Exciting New Class of
Semiconductor Nanomaterials. Chem. Mater. 2017, 29 (12),
ACKNOWLEDGMENT
This work was supported by “863” projects (Grant
2
015AA034203) and NSF of China (Grants 91622118,
91622124, 11474292 and 51602318), and ZSL acknowledges
the support from Youth Innovation Promotion Association,
CAS.
5
019ꢀ503.
(
18) Zheng, X.; Liu, Y.; Liu, G.; Liu, J.; Ye, X.; Han, Q.; Ge, C.;
Tao, X. Crystalline Mixed Halide Halobismuthates and Their
Induced Second Harmonic Generation. Chem. Mater. 2016, 28
REFERENCES
(
(
12), 4421ꢀ4431.
19) Cho, H.; Jeong, S.ꢀH.; Park, M.ꢀH.; Kim, Y.ꢀH.; Wolf, C.;
(
1) Stoumpos, C. C.; Malliakas, C. D.; Kanatzidis, M. G. Semiꢀ
Lee, C.ꢀL.; Heo, J. H.; Sadhanala, A.; Myoung, N.; Yoo, S.; Im, S.
H.; Friend, R. H.; Lee, T.ꢀW. Overcoming the electroluminesꢀ
cence efficiency limitations of perovskite lightꢀemitting diodes.
Science 2015, 350 (6265), 1222ꢀ1225.
conducting Tin and Lead Iodide Perovskites with Organic Catiꢀ
ons: Phase Transitions, High Mobilities, and NearꢀInfrared
Photoluminescent Properties. Inorg. Chem. 2013, 52 (15),
9
019ꢀ9038.
(
2 2 2
20) Wu, Q.; Meng, X.; Zhong, C.; Chen, X.; Qin, J. Rb CdBr I :
(
2) Burschka, J.; Pellet, N.; Moon, S. J.; HumphryꢀBaker, R.;
A New IR Nonlinear Optical Material with a Large Laser Damꢀ
age Threshold. J. Am. Chem. Soc. 2014, 136 (15), 5683ꢀ5686.
(21) Zhang, G.; Li, Y.; Jiang, K.; Zeng, H.; Liu, T.; Chen, X.; Qin,
J.; Lin, Z.; Fu, P.; Wu, Y.; Chen, C. A New Mixed Halide,
Gao, P.; Nazeeruddin, M. K.; Gratzel, M. Sequential deposition
as a route to highꢀperformance perovskiteꢀsensitized solar cells.
Nature 2013, 499 (7458), 316.
(
3) Dong, Q.; Fang, Y.; Shao, Y.; Mulligan, P.; Qiu, J.; Cao, L.;
Huang, J. Electronꢀhole diffusion lengths > 175 mu m in soluꢀ
tionꢀgrown CH NH PbI single crystals. Science 2015, 347
6225), 967ꢀ970.
4) Xing, G.; Mathews, N.; Lim, S. S.; Yantara, N.; Liu, X.; Sabꢀ
Cs
Material in the Infrared Region. J. Am. Chem. Soc. 2012, 134
36), 14818ꢀ14822.
(22) Huang, Y.; Meng, X.; Gong, P.; Lin, Z.; Chen, X.; Qin, J. A
study on K SbF Cl as a new midꢀIR nonlinear optical material:
new synthesis and excellent properties. J. Mater. Chem. C 2015,
(37), 9588ꢀ9593. 4.
23) Bekenev, V. L.; Khyzhun, O. Y.; Sinelnichenko, A. K.; Atuꢀ
2 2 2
HgI Cl : Molecular Engineering for a New Nonlinear Optical
3
3
3
(
(
(
ba, D.; Gratzel, M.; Mhaisalkar, S.; Sum, T. C. Lowꢀtemperature
solutionꢀprocessed wavelengthꢀtunable perovskites for lasing.
Nat. Mater. 2014, 13 (5), 476ꢀ480.
2
2
3
3
(
(
5) Wei, H.; Fang, Y.; Mulligan, P.; Chuirazzi, W.; Fang, H.ꢀH.;
chin, V. V.; Parasyuk, O. V.; Yurchenko, O. M.; Bezsmolnyy, Y.;
Kityk, A. V.; Szkutnik, J.; Calus, S. Crystal growth and the elecꢀ
Wang, C.; Ecker, B. R.; Gao, Y.; Loi, M. A.; Cao, L.; Huang, J.
Sensitive Xꢀray detectors made of methylammonium lead triꢀ
bromide perovskite single crystals. Nat. Photonics 2016, 10 (5),
tronic structure of Tl
05ꢀ713.
24) Atuchin, V. V.; Goloshumova, A. A.; Isaenko, L. I.; Jiang,
X.; Lobanov, S. I.; Zhang, Z.; Lin, Z. Crystal growth and elecꢀ
3 5
PbCl . J. Phys. Chem. Solids 2011, 72 (6),
7
(
3
33.
(
6) Atuchin, V. V.; Isaenko, L. I.; Kesler, V. G.; Tarasova, A. Y.
2 5
Single crystal growth and surface chemical stability of KPb Br .
J. Cryst. Growth 2011, 318 (1), 1000ꢀ1004.
4
tronic structure of lowꢀtemperature phase SrMgF . J. Solid
State Chem. 2016, 236, 89ꢀ93.
(
7) Atuchin, V. V.; Isaenko, L. I.; Kesler, V. G.; Pokrovsky, L. D.;
Tarasova, A. Y. Electronic parameters and top surface chemical
stability of RbPb Br . Mater. Chem. Phys. 2012, 132 (1), 82ꢀ86.
8) Isaenko, L. I.; Goloshumova, A. A.; Yelisseyev, A. P.; Shubin,
Y. V.; Khyzhun, O. Y.; Naumov, D. Y.; Tarasova, A. Y. New
SrPb Br crystals: Growth, crystal structure and optical properꢀ
ties. J. Alloys Compd. 2016, 682, 832ꢀ838.
(
25) Parasyuk, O. V.; Khyzhun, O. Y.; Piasecki, M.; Kityk, I. V.;
Lakshminarayana, G.; Luzhnyi, I.; Fochuk, P. M.; Fedorchuk, A.
O.; Levkovets, S. I.; Yurchenko, O. M.; Piskach, L. V. Synthesis,
structural, Xꢀray photoelectron spectroscopy (XPS) studies and
IR induced anisotropy of Tl HgI single crystals. Mater. Chem.
4 6
Phys. 2017, 187, 156ꢀ163.
2
5
(
3
8
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