Formation of trioxadamantane type aglucones of 3-methoxy secologanin derivatives

DOI: 10.1016/S0040-4020(97)00734-5

Source and publish data:

Tetrahedron p. 11659 - 11668 (1997)

Update date:2022-08-17

Topics:

Authors:

Krajsovszky, Gabor

Kocsis, Akos

Szabo, Laszlo Ferenc

Podanyi, Benjamin

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Article abstract of DOI:10.1016/S0040-4020(97)00734-5

Acidic transformation of some 3,4-dihydro-3-substituted secologanin derivatives produced trioxadamantane type compounds. The formation of the bridged tricyclic products from monocyclic educts is interpreted as multistep hydrolysis and transacetalation accompanied by deglucosylation.

Full text of DOI:10.1016/S0040-4020(97)00734-5

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