Bulletin of the Chemical Society of Japan p. 2143 - 2148 (1999)
Update date:2022-08-16
Topics:
Ai, Mamoru
Ohdan, Kyoji
Various mixed oxides were tested as catalysts for oxidative dehydrogenation of hydroxyacetone to form pyruvaldehyde (2-oxopropanal). The best results were obtained from an iron phosphate with a P/Fe atomic ratio of 1.05. The yield of pyruvaldehyde reached 88%. The next best results were obtained from a supported heteropoly acid (H3PMo12O40). The other molybdenum- and vanadium-based oxide catalysts were not suitable. The effects of the composition and structure of iron phosphate and the effects of reaction variables on the formation of pyruvaldehyde were also studied.
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