
Russian Chemical Bulletin p. 2452 - 2453 (1996)
Update date:2022-08-11
Topics:
Kazakov
Voloshin
Kabal'Nova
Shereshovets
Kazakov
Chemiluminescence (CL) was found upon the isomerization of dimethyldioxirane in the gas phase under argon atmosphere. The intensity of CL increases as temperature increases and decreases with time at constant temperature. If Silipor is placed in a cell containing the dimethyldioxirane vapor in argon, the intensity of CL sharply increases (more than 10 times) and then decreases following the exponential law. In all cases tripletly excited methyl acetate is the emitter of Chemiluminescence. 1997 Plenum Publishing Corporation.
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