Wavelength- and Temperature-dependent Photolysis of a Diphosphene. Generation of 2,4,6-Tri-t-butylphenylphosphinidene and E/Z Isomerization

DOI: 10.1246/cl.1988.1735

Source and publish data:

Chemistry Letters p. 1735 - 1738 (1988)

Update date:2022-08-17

Topics:

Authors:

Yoshifuji, Masaaki

Sato, Takahiro

Inamoto, Naoki

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Article abstract of DOI:10.1246/cl.1988.1735

A phospha-indane derivative was obtained via intramolecular C-H insertion of the phosphinidene generated as an intermediate by the photolysis of E-1,2-bis(2,4,6-tri-t-butylphenyl)diphosphene whereas the photolysis through a Pyrex filter at -40 ^{o
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Full text of DOI:10.1246/cl.1988.1735

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