Generation of Thioaldehydes from Sodium Thiosulphate S-Esters (Bunte Salts)

DOI: 10.1039/c39840000922

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 922 - 923 (1984)

Update date:2022-08-10

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Authors:

Kirby, Gordon W.

Lochead, Alistair W.

Sheldrake, Gary N.

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Article abstract of DOI:10.1039/c39840000922

Treatment of Bunte salts, ZCH2SSO3Na where Z is an electron-withdrawing group, with triethylamine and calcium chloride in the presence of cyclopentadiene or 2,3-dimethylbuta-1,3-diene gives the corresponding cycloadducts of the transient thioaldehydes, ZC

Full text of DOI:10.1039/c39840000922

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