Journal of the Chemical Society. Chemical communications p. 306 - 307 (1991)
Update date:2022-08-10
Topics:
Matsumoto, Kiyoshi
Hashimoto, Shiro
Otani, Shinichi
Even acyclic tertiary amines such as triethylamine, tri-n-propylamine and tri-n-butylamine, which have been believed to be inert to aromatic and heteroaromatic halides, underwent SNAr reactions with aromatic and heteroaromatic halides to give the dialkylamino derivatives; in the case of monocyclic amines like N-methylpyrrolidine and N-methylpiperidine, the dealkylation being regioselective.
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