Journal of the Chemical Society. Chemical communications p. 1203 - 1204 (1981)
Update date:2022-08-10
Topics:
Arnold, Donald R.
Yoshida, Masato
The Arrhenius kinetic parameters for the thermal cis-trans-isomerization of 1,2-di-(p-methoxyphenyl)-1,2-diphenyl- (1a), 1,2-di-(p-cyanophenyl)-1,2-diphenyl- (1b), 1-(p-cyanophenyl)-2-(p-methoxyphenyl)-1,2-diphenyl- (1c), and 1,2-di-(p-cyanophenyl)-1,2-di-(p-methoxyphenyl)-cyclopropane (1d) give an indication of the substituent effects on the stability of the transient 1,3-biradical.
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