STEREOSELECTIVE REDUCTION OF β-HYDROXYKETONES TO 1,3-DIOLS. HIGHLY SELECTIVE 1,3-ASYMMETRIC INDUCTION VIA BORON CHELATES

DOI: 10.1016/0040-4020(84)80006-X

Source and publish data:

Tetrahedron p. 2233 - 2238 (1984)

Update date:2022-08-03

Topics:

Authors:

Koichi, Narasaka

Pai, Fong-Chang

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Article abstract of DOI:10.1016/0040-4020(84)80006-X

Highly selective asymmetric induction can be achieved in the reduction of acyclic β-hydroxyketones via boron chelates.Treatment of β-hydroxyketones (1) with tributyl or triisobutylborane and successively with sodium borohydride afforded syn-1,3-diols (3)

Full text of DOI:10.1016/0040-4020(84)80006-X

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