Enantiomeric Resolution of a Germacrene-D Derivative by Chiral High-performance Liquid Chromatography

Article abstract of DOI:10.1271/bbb.61.547

Direct enantiomeric resolution of the germacrene-D derivative, (5E,7S*,9S*)-9-hydroxy-7-isopropyl-4,10-bis(methylene)-5-cyclodecen- 1-one, was carried out by HPLC with a chiral stationary phase. This method showed that germacrene-D contained in ylang ylang oil was 98% e.e., whereas germacrene-D extracted from Solidago altissima L. was almost racemic.

Full text of DOI:10.1271/bbb.61.547

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Bioscience, Biotechnology, and Biochemistry
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Enantiomeric Resolution of a Germacrene-D
Derivative by Chiral High-performance Liquid
Chromatography
Yoshinori Nishiia, Taichi Yoshidaa & Yoo Tanabea
a School of Science, Kwansei Gakuin University, 1-1-155 Uegahara, Nishinomiya, Hyogo
662, Japan
Published online: 12 Jun 2014.
To cite this article: Yoshinori Nishii, Taichi Yoshida & Yoo Tanabe (1997) Enantiomeric Resolution of a Germacrene-
D Derivative by Chiral High-performance Liquid Chromatography, Bioscience, Biotechnology, and Biochemistry, 61:3,
547-548, DOI: 10.1271/bbb.61.547
To link to this article: http://dx.doi.org/10.1271/bbb.61.547
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