Rhodium(II)-catalyzed reaction of 1,3-bis(diazo)indan-2-one with alcohols: Formation of unexpected 1,1-dialkoxy ketones

DOI: 10.1016/0040-4039(95)00069-O

Source and publish data:

Tetrahedron Letters p. 1499 - 1502 (1995)

Update date:2022-08-10

Topics:

Authors:

Murata, Shigeru

Kongou, Chiharu

Tomioka, Hideo

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Article abstract of DOI:10.1016/0040-4039(95)00069-O

The rhodium(II)-catalyzed decomposition of 1,3-bis(diazo)indan-2-one (1) in boiling dichloromethane containing primary alcohols gave 1,1-dialkoxyindan-2-ones (2) in good yields without any formation of 1,3-dialkoxy derivatives.

Full text of DOI:10.1016/0040-4039(95)00069-O

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