Russian Chemical Bulletin p. 1326 - 1329 (1993)
Update date:2022-08-11
Topics:
Shul'pin, G. B.
Druzhinina, A. N.
Nizova, G. V.
Aromatic hydrocarbons are oxidized with hydrogen peroxide in the presence of catalytic amounts of VO3- and pyrazine-2-carboxylic acid into phenols (provided excess hydrocarbon is used) or into quinones (at high H2O2 concentrations). 2-Propanol, ethanol, cyclohexanol, and benzyl alcohol are transformed into the corresponding aldehydes and ketones under the same conditions (without a solvent or in MeCN). - Key words: oxidation, hydrogen peroxide, vanadium complexes; aromatic hydrocarbons; alcohols.
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