DICYCLOPENTADIENYL-NIOBIUM(III) AND -NIOBIUM(IV) COMPLEXES

DOI: 10.1016/0022-328X(82)80006-5

Source and publish data:

Journal of Organometallic Chemistry p. 309 - 314 (1982)

Update date:2022-08-16

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Authors:

Antinolo, A.

Fajardo, M.

Otero, A.

Royo, P.

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Article abstract of DOI:10.1016/0022-328X(82)80006-5

The reduction of (η-C5H5)2NbCl2 (I) under various conditions gives the dimer (η-C5H5)4Nb2Cl3 (II) containing niobium(III) and niobium(IV).Reaction of II with AgClO4 gives <(η-C5H5)4Nb2Cl2>⁺ ClO4^- (III).FeCl3 and (C6F5)2TlBr displace

Full text of DOI:10.1016/0022-328X(82)80006-5

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