Synthesis of Bis(α-amino acids) by Palladium-catalyzed Allylic Double Substitution

DOI: 10.1016/0040-4039(95)01574-2

Source and publish data:

Tetrahedron Letters p. 7697 - 7700 (1995)

Update date:2022-08-11

Topics:

Authors:

Mazon, Angel

Najera, Carmen

Ezquerra, Jesus

Pedregal, Concepcion

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Article abstract of DOI:10.1016/0040-4039(95)01574-2

The reaction of lithium enolate derived from benzophenone imine of glycine ethyl ester 1 with allylic dihalides 2 in the presence of a catalytic amount of Pd(PPh3)4 (5percent mol) affords the corresponding bis(imino esters) 3.Subsequent hydrolysis of comp

Full text of DOI:10.1016/0040-4039(95)01574-2

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