Tetrahedron p. 5465 - 5474 (1985)
Update date:2022-07-29
Topics:
Mori, Miwako
Kanda, Nana
Oda, Izumi
Ban, Yoshio
α-Haloamide having internal double bond was allowed to react with a catalytic amount of Pd(PPh3)4 in the presence of base to produce a cyclized product in a fairly good yield possibly through the intermediate of -alkylmetal complex. By use of this method, five and six membered lactams, pyrrolizidine and quinolizidine derivatives were synthesized in fairly good yields.
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(2017)
