
Journal of the Chemical Society. Chemical communications p. 1067 - 1068 (1984)
Update date:2022-08-11
Topics:
Roman, Enrique
Hernandez, Sergio
Barrera, Mauricio
Hexamethyl(Dewar benzene) (HMDB) isomerizes to hexamethylbenzene (HMB) under visible light irradiation in the presence of stoicheiometric or catalytic amounts of the cationic complexes <(η5-C5R5)Fe(η6-arene)>+X-, (R = H, Me; X = BF4-, PF6-), (1a - e) and (2), in dichloromethane solutions at 273 K; mixtures of HMDB and (1b - e) or (2) in dichloromethane exhibit a luminescence band at 530 - 540 nm probably due to formation of the corresponding exciplex.
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