Preparations of Bicyclic Chiral Lactone Synthons via Stereospecific Pig Liver Esterase-catalysed Hydrolyses of meso-Diesters. Ring-size induced Reversal of Stereospecificity

DOI: 10.1039/c39840000236

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Journal of the Chemical Society. Chemical communications p. 236 - 238 (1984)

Update date:2022-08-30

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Authors:

Sabbioni, Gabriele

Shea, Marion L.

Jones, J. Bryan

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Article abstract of DOI:10.1039/c39840000236

Stereospecific pig liver esterase-catalysed hydrolysis of monocyclic meso-1,2-diesters provides a convenient preparative route to both enantiomers of useful chiral lactones and demonstrates a sharply defined and unprecedented ring-size-mediated reversal of stereospecificity.

Full text of DOI:10.1039/c39840000236

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