Stereoselective synthesis of (-)-(5R,6S)-6-acetoxy-5-hexadecanolide, the mosquito oviposition attractant pheromone

DOI: 10.1016/S0040-4020(01)86684-9

Source and publish data:

Tetrahedron p. 1191 - 1198 (1990)

Update date:2022-08-16

Topics:

Authors:

Wang, Zhi-Min

Qian, Xin-Hua

Zhou, Wei-Shan

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Article abstract of DOI:10.1016/S0040-4020(01)86684-9

The natural mosquito oviposition attractant pheromone,(-)-(5R,6S)- 6-acetoxy-5-hexadecanolide (1) was synthesized from readily available 1,2-cyclohexanediol, using kinetic resolution of cyclic allylic alcohol by modified Sharpless asymmetric epoxidation reagent as the key step.

Full text of DOI:10.1016/S0040-4020(01)86684-9

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Product name:(6S)-Tetrahydro-6-[(R)-1-hydroxyundecyl]-2H-pyran-2-one

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