Does the threshold enantiomerization route of crowded tetraarylethenes involve double bond rotation?

DOI: 10.1021/ja00143a010

Source and publish data:

Journal of the American Chemical Society p. 9686 - 9689 (1995)

Update date:2022-08-11

Topics:

Authors:

Maeda, Katsuhiro

Okamoto, Yoshio

Morlender, Natalia

Haddad, Nizar

Eventova, Irina

Biali, Silvio E.

Rappoport, Zvi

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Article abstract of DOI:10.1021/ja00143a010

The chiral tetraarylvinyl propeller 1,2-bis(4-tert-butyl-2,6-dimethylphenyl)-1,2-dimesitylethene (4) was synthesized by irradiation of (4-tert-butyl-2,6-dimethylphenyl)mesitylketene 5. Ethene 4 exists in two diastereomeric forms (E and Z), each existing a

Full text of DOI:10.1021/ja00143a010

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Product name:Ethenone, [4-(1,1-dimethylethyl)-2,6-dimethylphenyl](2,4,6-trimethylphenyl)-

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