Helvetica Chimica Acta p. 181 - 184 (1985)
Update date:2022-09-26
Topics:
Ziegler, Carl B. Jr.
Fischli, Albert
During the cob(I)alamin(1(I))-catalyzed reduction of 3, intermediate formation of 2 and final generation of 4-10 was observed (see Scheme 1, cf.Tables 1 and 2).Identical products in similar ratios were generated starting from either 2 or 3.Accepting the intermediate formation of six interconnected cobalt complexes, i.e.A-F (cf.Sceme 2), the generation of all the products observed can be explained.
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