CYCLOPROPANATION USING RHODIUM(III)PORPHYRINS : LARGE CIS VS TRANS SELECTIVITY

DOI: 10.1016/S0040-4039(00)78722-3

Source and publish data:

Tetrahedron Letters p. 3489 - 3492 (1980)

Update date:2022-08-31

Topics:

Authors:

Callot, H. J.

Piechocki, C.

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Article abstract of DOI:10.1016/S0040-4039(00)78722-3

Rhodium(III)tetraphenylporphyrin behaves as a sterically hindered cyclopropanation catalyst.Cis-cyclopropanes or "abnormal" products are obtained on reaction with cis-olefins or aromatics.

Full text of DOI:10.1016/S0040-4039(00)78722-3

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