CYCLOPROPANATION USING RHODIUM(III)PORPHYRINS : LARGE CIS VS TRANS SELECTIVITY

DOI: 10.1016/S0040-4039(00)78722-3

Source and publish data:

Tetrahedron Letters p. 3489 - 3492 (1980)

Update date:2022-08-31

Topics:

Authors:

Callot, H. J.

Piechocki, C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)78722-3

Rhodium(III)tetraphenylporphyrin behaves as a sterically hindered cyclopropanation catalyst.Cis-cyclopropanes or "abnormal" products are obtained on reaction with cis-olefins or aromatics.

Full text of DOI:10.1016/S0040-4039(00)78722-3

Products guided by the article

Product name:ethyl (1R,2S)-2-phenylcyclopropanecarboxylate

Cas No:946-38-3

R&D Labs maybe for 946-38-3

Xuzhou Tianrun Chemical Co.,Ltd

website:http://www.tianrunchem.cn

Contact:86-516-83832636

Address:fuxing road
HaiNan Periwinkle Pharmaceutical Co.,Ltd.

website:http://www.cchpharm.com/en/index.html

Contact:020-82208978

Address:Gongye road,Wuzhishan city,HaiNan province
Chinese Peptide Company

Contact:86-571-86737118-8689

Address:No.69, 12 Street, HEDA, Hangzhou, Zhejiang, China
qingdao goldenchem imp and exp co.,ltd.

Contact:532-55579246

Address:no.62 ,haier road laoshan distirct
Pale Palm Imex

Contact:+36(21)2523420

Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA

Relevant to this article

Unsaturated nitriles: Precursors for a domino ozonolysis-aldol synthesis of oxonitriles

Doi:10.1021/jo9822885
(1999)
Alkali metal cations control over nucleophilic substitutions on aromatic fused pyrimidine-2,4-[1H,3H]-diones: Towards new PNA monomers

Doi:10.1016/j.tet.2012.08.028
(2012)
Nickel-Catalyzed Trifluoromethylselenolation of Aryl Halides Using the Readily Available [Me₄N][SeCF₃] Salt

Doi:10.1021/acs.orglett.7b01839
(2017)
Studies towards the Synthesis of the Antibiotic Tetrodecamycin

Doi:10.1055/s-0037-1609303
(2018)
A Remarkable Effect of Aluminum on the Novel and Efficient Aqueous-Phase Hydrogenation of Levulinic Acid into Γ-Valerolactone Using Water-Soluble Platinum Catalysts Modified with Nitrogen-Containing Ligands

Doi:10.1007/s10562-019-02707-9
(2019)
Synthesis of fluorine compounds using zinc complex of halothane

Doi:10.1016/0040-4020(96)00722-3
(1996)

Article Doi