CYCLOPROPANATION USING RHODIUM(III)PORPHYRINS : LARGE CIS VS TRANS SELECTIVITY

DOI: 10.1016/S0040-4039(00)78722-3

Source and publish data:

Tetrahedron Letters p. 3489 - 3492 (1980)

Update date:2022-08-31

Topics:

Authors:

Callot, H. J.

Piechocki, C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)78722-3

Rhodium(III)tetraphenylporphyrin behaves as a sterically hindered cyclopropanation catalyst.Cis-cyclopropanes or "abnormal" products are obtained on reaction with cis-olefins or aromatics.

Full text of DOI:10.1016/S0040-4039(00)78722-3

Products guided by the article

Product name:ethyl (1R,2S)-2-phenylcyclopropanecarboxylate

Cas No:946-38-3

R&D Labs maybe for 946-38-3

Wuhan Chemchemical Co., Ltd.(expird)

Contact:15973022782

Address:7-5-6218,Incubation Centre,Guandong Industry Park, East Lake High-Tech Development Zone,Wuhan City.
Shanghai better-in Medical Technology Co.,LTD.

Contact:+86-21-38921049

Address:Lane 720 zhangjianggaoke cailun road, Pudong, Shanghai, room 513
Shanghai Rainbow Chemistry Co., Ltd.

Contact:+86-21-64968086-5815/5812

Address:3rd floor, Building 7, 251 Faladi Road, Zhangjiang Hi-Tech Park, Pudong District, Shanghai, P.R. China
HAINAN JINYING IMPORT AND EXPORT CO. LTD

Contact:+86-898-32875423

Address:A SECTION 19TH FL, TIMES SQUARE, NO.2 GUO MAO AVENUE HAIKOU, HAINAN, P. R. OF CHINA
Shandong Bolode Bio-Technology Co., LTD

Contact:+86-0531-58966870

Address:136 Jingyi Road,Huaiyin District,Jinan,Shandong,China

Relevant to this article

Unsaturated nitriles: Precursors for a domino ozonolysis-aldol synthesis of oxonitriles

Doi:10.1021/jo9822885
(1999)
Alkali metal cations control over nucleophilic substitutions on aromatic fused pyrimidine-2,4-[1H,3H]-diones: Towards new PNA monomers

Doi:10.1016/j.tet.2012.08.028
(2012)
Nickel-Catalyzed Trifluoromethylselenolation of Aryl Halides Using the Readily Available [Me₄N][SeCF₃] Salt

Doi:10.1021/acs.orglett.7b01839
(2017)
Studies towards the Synthesis of the Antibiotic Tetrodecamycin

Doi:10.1055/s-0037-1609303
(2018)
A Remarkable Effect of Aluminum on the Novel and Efficient Aqueous-Phase Hydrogenation of Levulinic Acid into Γ-Valerolactone Using Water-Soluble Platinum Catalysts Modified with Nitrogen-Containing Ligands

Doi:10.1007/s10562-019-02707-9
(2019)
Synthesis of fluorine compounds using zinc complex of halothane

Doi:10.1016/0040-4020(96)00722-3
(1996)

Article Doi