Energy-Minimized Structures and Calculated and Experimental Isomer Distributions in the Hexaamine-Cobalt(III) System 3+ with the Chiral Facially-Coordinating Triamine (L=Butane-1,2,4-Triamine)

Article abstract of DOI:10.1002/hlca.19890720520

Butane-1,2,4-triamine (trab) is the smallest tridentate aliphatic unsubstituted chiral triamine.With optically pure trab, there are three, with racemic trab five isomers of 3+.One of the five isomers is centrosymmetrical, the others are chiral.