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Gallium trichloride

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Name

Gallium trichloride

EINECS 236-610-0
CAS No. 13450-90-3 Density 2.47 g/mL at 25 °C(lit.)
PSA 0.00000 LogP 1.68770
Solubility Soluble in water Melting Point 78 °C(lit.)
Formula GaCl3 Boiling Point 35 °C
Molecular Weight 176.082 Flash Point -26 °F
Transport Information UN 3260 Appearance white crystals or powder
Safety 26-27-28-36/37/39-45 Risk Codes 14-34
Molecular Structure Molecular Structure of 13450-90-3 (GALLIUM(III) CHLORIDE) Hazard Symbols CorrosiveC
Synonyms

Gallium(III) chloride;Gallium chloride;Gallium trichloride;NSC 94002;Trichlorogallium;Gallium(3+) chloride;

Article Data 60

Gallium trichloride Synthetic route

7440-55-3

gallium

7782-50-5

chlorine

13450-90-3

Gallium trichloride

Conditions
ConditionsYield
In melt 5 mol% excess of gaseous chlorine passed through metal gallium melt;99%
excess Cl2;;
mixt. heating (two-section glass tube, 200-250°C); vac. sublimation (water pump, ca. 250°C);
13886-65-2

gallium hydrogen dichloride

98127-35-6

1,2,4,5-tetrakis((trimethylsilyl)ethynyl)benzene

A

950696-91-0

C6H2((CHC(Si(CH3)3))2GaCl(O(C2H5)2))2

B

13450-90-3

Gallium trichloride

Conditions
ConditionsYield
In hexane under Ar; soln. of HGaCl2 in n-hexane treated with soln. of (Me3SiC2)4C6H2 in n-hexane at room temp.; heated under reflux for 14 h; filtered; ppt. washed with n-hexane; treated with Et2O; filtered; filtrate concd.; cooled to -45°C; elem. anal.;A 46%
B n/a

gallium(III) oxide

ammonium chloride

13450-90-3

Gallium trichloride

Conditions
ConditionsYield
In neat (no solvent) heating up to 250 °C;;
In neat (no solvent) heating up to 250 °C;;

gallium(III) oxide

7719-09-7

thionyl chloride

13450-90-3

Gallium trichloride

Conditions
ConditionsYield
In neat (no solvent) 200°C;;
In neat (no solvent) 200°C;;

gallium(III) oxide

10026-04-7, 53609-55-5

tetrachlorosilane

A

13450-90-3

Gallium trichloride

Conditions
ConditionsYield
300-350°C in vac.; Two-fold vacuum sublimation with prior distilling off SiCl4.;
7440-55-3

gallium

7783-90-6

silver(I) chloride

13450-90-3

Gallium trichloride

Conditions
ConditionsYield
In neat (no solvent, solid phase) byproducts: Ag; oven (cf. Grabandt, de Lange, Mooyman, Chem. Phys. Lett. 160 (1989) 359) filled with a mixt. of gallium metal and AgCl, oven temp. between 700 to 900°C, inner ionization chamber kept at low temp.; not isolated, detected by photoelectron spectra;

gallium arsenide

A

13450-90-3

Gallium trichloride

B

7784-34-1

arsenic trichloride

Conditions
ConditionsYield
With Cl2 Kinetics; GaAs wafer, 25-150°C, pressure from 0.09 to 20 Torr of Cl2;
1445-79-0

trimethyl gallium

A

13450-90-3

Gallium trichloride

B

6917-81-3

dimethylchlorogallane

C

6917-74-4

methylgallium dichloride

Conditions
ConditionsYield
With HCl In neat (no solvent, gas phase)
With HCl In diethyl ether
7440-55-3

gallium

13450-90-3

Gallium trichloride

Conditions
ConditionsYield
With chlorine In neat (no solvent) Ar atmosphere; chlorination by 120°C; distn. (flow of chloridine), resublimation (flow of Ar);
With Cl2 200-250°C;
With Cl2 chlorination; sublimation;
7647-01-0

hydrogenchloride

7440-55-3

gallium

13450-90-3

Gallium trichloride

Conditions
ConditionsYield
gentle heating;;
In neat (no solvent) Ga metal was dissolved in concd. HCl;

Gallium trichloride Consensus Reports

Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances List.

Gallium trichloride Specification

The Gallium trichloride  with CAS registry number of 13450-90-3 is also known as Gallium trichloride. The IUPAC name and product name are the same. It belongs to product categories of Inorganics; Crystal Grade Inorganics; Catalysis and Inorganic Chemistry; Chemical Synthesis; Gallium Salts; GalliumMetal and Ceramic Science; Salts. Its EINECS registry number is 236-610-0. In addition, the formula is GaCl3 and the molecular weight is 176.08. This chemical is a white crystals or powder and should be sealed in a ventilated, cool and dry place at room temperature. What's more, it is used as organic catalyst.

Physical properties about Gallium trichloride are:
 (1)Exact Mass: 173.832139; (2)MonoIsotopic Mass: 173.832139; (3)Heavy Atom Count: 4; (4)Complexity: 8; (5)Covalently-Bonded Unit Count: 1;(6)#H bond acceptors:  0; (7)#H bond donors:  0; (8)#Freely Rotating Bonds:  0.

Preparation of Gallium trichloride: 
It is prepared by reaction of gallium oxide with thionyl chloride. Firstly, the reaction mixture is heated to 200 °C until gallium oxide is chlorinated completely. Then the reaction mixture is cooled to -10 °C and distilled to remove the excess thionyl chloride. At last, product is refined by distillating at 220 °C.

Safety information of Gallium trichloride:
When you are using this chemical, please be cautious about it. As a chemical, it is extremely flammable and causes burns. It reacts violently with water and it is toxic to aquatic organisms that may cause long-term adverse effects in the aquatic environment. During using it, wear suitable protective clothing, gloves and eye/face protection. Keep away from sources of ignition and avoid release to the environment. After contact with skin, take off immediately all contaminated clothing, and wash immediately. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If accident happens or you feel unwell seek medical advice immediately. What's more, do not empty into drains and take precautionary measures against static discharges.

You can still convert the following datas into molecular structure:
(1)SMILES:Cl[Ga](Cl)Cl;
(2)Std. InChI:InChI=1S/3ClH.Ga/h3*1H;/q;;;+3/p-3;
(3)Std. InChIKey:UPWPDUACHOATKO-UHFFFAOYSA-K;

The toxicity data of Gallium trichloride is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LD50 intravenous 41mg/kg (41mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
mouse LD50 intraperitoneal 36975ug/kg (36.975mg/kg)   Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. Vol. 256, Pg. 1043, 1963.
rabbit LD50 intravenous 43mg/kg (43mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rabbit LD50 subcutaneous 245mg/kg (245mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rat LCLo inhalation 316mg/m3/3H (316mg/m3)   Journal of Pharmacology and Experimental Therapeutics. Vol. 95, Pg. 487, 1949.
rat LD50 intravenous 47mg/kg (47mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rat LD50 parenteral 1408mg/kg (1408mg/kg)   AJR, American Journal of Roentgenology. Vol. 142, Pg. 619, 1984.
rat LD50 subcutaneous 306mg/kg (306mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.

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