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Name	Glutaric acid	EINECS	203-817-2
CAS No.	110-94-1	Density	1.316 g/cm³
PSA	74.60000	LogP	0.32590
Solubility	430 g/L (20 °C) in water	Melting Point	95-98 °C(lit.)
Formula	C₅H₈O₄	Boiling Point	302.894 °C at 760 mmHg
Molecular Weight	132.116	Flash Point	151.2 °C
Transport Information	N/A	Appearance	white or off-white crystals
Safety	26-37/39-36	Risk Codes	36/37/38
Molecular Structure		Hazard Symbols	Xi
Synonyms	Glutaricacid (8CI);1,3-Propanedicarboxylic acid;1,5-Pentanedioic acid;NSC 9238;	Article Data	476

Glutaric acid Synthetic route

: 13246-39-4
(+-)-1-(trimethylsilyl)ethanol

: 53715-97-2
5,5'-oxybis(5-oxopentanoic acid)

: 110-94-1
1,5-pentanedioic acid

Conditions

Conditions	Yield
With dmap; triethylamine In dichloromethane	100%

: 111-29-5
1 ,5-pentanediol

: 110-94-1
1,5-pentanedioic acid

Conditions

Conditions	Yield
With C24H33IrN4O3; water; sodium hydroxide for 18h; Catalytic behavior; Reagent/catalyst; Reflux;	98%
In water for 48h; Ambient temperature; Gluconobacter roseus IAM 1841;	97%
With sodium hydroxide In water at 20℃; Temperature; Concentration; Electrochemical reaction;	91%

: 5057-98-7
cis-1,2-cyclopentanediol

: 110-94-1
1,5-pentanedioic acid

Conditions

Conditions	Yield
With dihydrogen peroxide; Na12[WZn3(H2O)2(ZnW9O34)2] at 75℃; for 7h;	98%

: 765-87-7
cyclohexane-1,2-dione

: 110-94-1
1,5-pentanedioic acid

Conditions

Conditions	Yield
With ozone In tetrachloromethane; water at 20℃; for 1h; UV-irradiation;	97%
With water; ozone at 25℃; under 760.051 Torr; for 1h; Irradiation;	95%
With oxygen; sodium hydroxide In water at 90℃; under 3000.3 Torr; for 3h; pH=7;	21%

: 5057-99-8
trans-cyclopentane-1,2-diol

: 110-94-1
1,5-pentanedioic acid

Conditions

Conditions	Yield
With hydrogenchloride; sodium tungstate; phosphoric acid; dihydrogen peroxide at 90℃; for 5h;	96%

: 96-41-3
Cyclopentanol

: 110-94-1
1,5-pentanedioic acid

Conditions

Conditions	Yield
Stage #1: Cyclopentanol With Oxone; ruthenium(III) chloride monohydrate In water at 70℃; for 8h; Stage #2: In ethanol Cooling;	95%
With nitric acid at 70 - 100℃;
With nitric acid; vanadia at 70 - 100℃;

: 120-92-3
cyclopentanone

: 110-94-1
1,5-pentanedioic acid

Conditions

Conditions	Yield
With oxygen; trifluoroacetic acid; sodium nitrite at 0 - 20℃; for 5.25h; Product distribution / selectivity;	95%
Stage #1: cyclopentanone With Oxone; ruthenium(III) chloride monohydrate In water at 20℃; for 5h; Stage #2: In ethanol Cooling;	90%
With oxygen; copper dichloride In acetic acid at 80℃; for 6h; Oxidation;	84%

: 142-29-0
cyclopentene

: 110-94-1
1,5-pentanedioic acid

Conditions

Conditions	Yield
With potassium metaperiodate; potassium aquapentachlororuthenate(III) In dichloromethane; water; acetonitrile at 20℃; for 2h; Catalytic behavior; Sonication;	94%
With potassium permanganate; H-montmorillonite In water; benzene at 25 - 30℃; for 1h;	90%
With periodic acid; cis-[RuCl2(bipy)2]*2H2O In tetrachloromethane; water; acetonitrile at 20℃; for 2h;	85%

: 504-02-9
1,3-cylohexanedione

: 110-94-1
1,5-pentanedioic acid

Conditions

Conditions	Yield
With triethylmethylammonium iodide; water; dihydrogen peroxide In acetonitrile at 55℃; for 23h;	94%
With potassium carbonate In water at 25℃; Electrochemical reaction;	81%
With iodine; oxygen In ethyl acetate for 10h; Mercury lamp irradiation;	40%

: 930-68-7
cyclohexenone

oxone: oxone

Os(VIII): Os(VIII)

: 110-94-1
1,5-pentanedioic acid

Conditions

Conditions	Yield
With hydrogenchloride; sodium sulfate; OsO4 In ethyl acetate; N,N-dimethyl-formamide; tert-butyl alcohol	92%

Glutaric acid Chemical Properties

The Molecular Structure of Glutaric acid (CAS NO.110-94-1):

Empirical Formula: C₅H₈O₄
Molecular Weight: 132.1146
IUPAC Name: pentanedioic acid
Appearance: white or off-white crystals
Nominal Mass: 132 Da
Average Mass: 132.1146 Da
Monoisotopic Mass: 132.042259 Da
Index of Refraction: 1.476
Molar Refractivity: 28.34 cm³
Molar Volume: 100.3 cm³
Surface Tension: 56.1 dyne/cm
Density: 1.316 g/cm³
Flash Point: 151.2 °C
Enthalpy of Vaporization: 59.74 kJ/mol
Boiling Point: 302.9 °C at 760 mmHg
Vapour Pressure: 0.000223 mmHg at 25°C
Product Categories: Pharmaceutical Intermediates;alpha,omega-Alkanedicarboxylic Acids;alpha,omega-Bifunctional Alkanes;Monofunctional & alpha,omega-Bifunctional Alkanes;C1 to C5;Carbonyl Compounds;Carboxylic Acids
Water Solubility: 430 g/L (20 ºC)
Stability: Stable. Incompatible with bases, oxidizing agents, reducing agents
Synonyms: 1,3-Propanedicarboxylic acid ; 1,5-Pentanedioic acid ; 4-02-00-01934 (Beilstein Handbook Reference) ; AI3-24247 ; BRN 1209725 ; EINECS 203-817-2 ; GLUTARIC ACID ; Pentandioic acid ; Pentanedioic acid ; n-Pyrotartaric acid ; Pentanedioic acid

Glutaric acid Uses

Glutaric acid (CAS NO.110-94-1), a common plasticizer and precursor to polyesters is manufactored by hydrogenation of Glutaric acid (CAS NO.110-94-1) and its derivatives. Glutaric acid (NO.110-94-1) itself has been used in the production of polymers such as polyester polyols, polyamides. The odd number of carbon atoms (i.e. 5) is useful in decreasing polymer elasticity.

Glutaric acid Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	oral	6gm/kg (6000mg/kg)		Biochemical Journal. Vol. 34, Pg. 1196, 1940.

RTECS#: CAS# 110-94-1: MA3740000
LD50/LC50: RTECS:
CAS# 110-94-1: Oral, mouse: LD50 = 6 gm/kg;
Carcinogenicity: Glutaric acid - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Other: See actual entry in RTECS for complete information. The toxicological properties have not been fully investigated.

Glutaric acid Safety Profile

Hazard Codes: Irritant Xi
Risk Statements: 36-36/37/38
R36: Irritating to eyes
R36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements: 26-37/39-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S37/39: Wear suitable gloves and eye/face protection
S36: Wear suitable protective clothing
WGK Germany: 1
RTECS: MA3740000
HS Code: 29171990

Glutaric acid Specification

Personal Protection：
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Fire Fighting：Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
Product Categories: Pharmaceutical Intermediates;alpha,omega-Alkanedicarboxylic Acids;alpha,omega-Bifunctional Alkanes;Monofunctional & alpha,omega-Bifunctional Alkanes;C1 to C5;Carbonyl Compounds;Carboxylic Acids

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