Silanecarboxamide, pentamethyl- (9CI)

Base Information

• Chemical Name: Silanecarboxamide, pentamethyl- (9CI)
• CAS No.: 479486-96-9
• Molecular Formula: C6H15NOSi
• Molecular Weight: 145.277
• Mol file: 479486-96-9.mol

Synonyms:pentamethylsilanecarboxamide;N,N-dimethylcarbamoyl(trimethyl)silane;[N,N-dimethylcarbamoyl]trimethylsilane;N,N-dimethyl(trimethylsilyl)methaneamide;N,N-dimethyl (trimethylsilyl)methanamide;(N,N-dimethylcarbamoyl)trimethylsilane;

Chemical Property of Silanecarboxamide, pentamethyl- (9CI)

Chemical Property:

• Boiling Point: 37-41 °C(Press: 0.9 Torr)
• PKA: -0.11±0.70(Predicted)
• PSA: 20.31000
• Density: 0.866±0.06 g/cm3(Predicted)
• LogP: 1.58790

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Silanecarboxamide, pentamethyl- (9CI)

There total 1 articles about Silanecarboxamide, pentamethyl- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

chloro-trimethyl-silane (75-77-4) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → N,N-dimethyl (trimethylsilyl)methanamide (479486-96-9)

Guidance literature:

With lithium diisopropyl amide; In tetrahydrofuran; hexane; at -78 - 20 ℃;

DOI:10.1081/SCC-120020211

Reference yield: 95.0%

ethyl 2-(4-chlorophenyl)-2-oxoacetate (34966-48-8) + N,N-dimethyl (trimethylsilyl)methanamide (479486-96-9) → C16H24ClNO4Si

Guidance literature:

In toluene; at 60 ℃; for 27h;

DOI:10.1016/j.tetlet.2015.05.073

Reference yield: 92.0%

diphenylchloromethane (90-99-3) + N,N-dimethyl (trimethylsilyl)methanamide (479486-96-9) → diphenamid (957-51-7)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; at 100 ℃; for 12h;

DOI:10.1021/jo0512406

upstream raw materials:

chloro-trimethyl-silane

N,N-dimethyl-formamide

Downstream raw materials:

N, N-dimethylthiophene-2-carboxamide

N,N-dimethylbenzamide

N,N-dimethyl-4-methoxybenzamide

N,N,2,4,6-pentamethylbenzamide