Iron(3+) ethanolate

Base Information

• Chemical Name: Iron(3+) ethanolate
• CAS No.: 5058-42-4
• Molecular Formula: C2H6 O . 1/3 Fe
• Molecular Weight: 191.03
• European Community (EC) Number: 225-760-2
• DSSTox Substance ID: DTXSID20198599
• Nikkaji Number: J203.272D
• Mol file: 5058-42-4.mol

Synonyms:Iron(3+) ethanolate;5058-42-4;IRON(III) ETHOXIDE;ethanolate;iron(3+);EINECS 225-760-2;Triethoxyiron(III);C2H6O.1/3Fe;C2-H6-O.1/3Fe;DTXSID20198599;AKOS025295391;FT-0750133

Chemical Property of Iron(3+) ethanolate

Chemical Property:

• Vapor Pressure: 82.8mmHg at 25°C
• Melting Point: 120°C
• Boiling Point: 78°C
• Flash Point: 12°C
• PSA: 27.69000
• Density: 0,87 g/cm3
• LogP: 1.45910
• Sensitive.: Moisture Sensitive
• Solubility.: Soluble in anhydrous hexane, alcohols.Miscible with hexane, benz
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 191.037055
• Heavy Atom Count: 10
• Complexity: 2.8

Purity/Quality:

99% ^*data from raw suppliers

Iron(III) ethoxide, 99.6% (metals basis) ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[O-].CC[O-].CC[O-].[Fe+3]
• Uses: Precursor for Sol-Gel processes.Iron(III) ethoxide is used as a precursor for inorganic compound iron oxide. It is used in the preparation of iron-platinum nanoparticles by pyrolysis with platinum(II) acetylacetonate.

Technology Process of Iron(3+) ethanolate

There total 11 articles about Iron(3+) ethanolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iron(III) chloride + sodium methylate (124-41-4) → iron(III) ethoxide (5058-42-4)

Guidance literature:

In hexane; at 110 ℃; for 3h; Inert atmosphere;

Reference yield:

iron(III) ethoxide → iron(III) ethoxide (5058-42-4)

Guidance literature:

With titanium ethoxide; niobium ethoxide; In ethanol; addn. of alc. soln. of Ti-ethoxide and Nb-ethoxide to Fe10(OC2H5)22O4*nC2H5OH;; pptn.; washing with hot abs. ethanol and drying in vac.; elem. anal.;;

Reference yield:

sodium ethanolate (141-52-6) + iron(III) chloride (7705-08-0) → iron(III) ethoxide (5058-42-4)

Guidance literature:

In ethanol; byproducts: NaCl; filtration from NaCl;;

upstream raw materials:

ethanol

potassium ethoxide

iron(III) chloride

sodium ethanolate

Downstream raw materials:

tris(4'-methoxyflavonolato)iron(II)

Refernces

• 1、 Lu, Chang-Wei,Wang, Qun,Chen, Yun-Xian,Shi, Jian-Lin. "Simultaneous characterizing study of the metallic iron-organic coordination compounds by TG-DSC-MS coupling techniques". . p. 63 - 70. Retrieved 2003.
• 2、 Bekhradnia, Ahmadreza,Norrby, Per-Ola. "New insights into the mechanism of iron-catalyzed cross-coupling reactions". . p. 3959 - 3962. Retrieved 2015/04/27.