N-(diphenylmethylidene)-1-phenylmethanamine

Base Information

• Chemical Name: N-(diphenylmethylidene)-1-phenylmethanamine
• CAS No.: 7699-79-8
• Molecular Formula: C20H17N
• Molecular Weight: 271.362
• Mol file: 7699-79-8.mol

Synonyms:

Chemical Property of N-(diphenylmethylidene)-1-phenylmethanamine

Chemical Property:

• Vapor Pressure: 6.27E-06mmHg at 25°C
• Boiling Point: 389.7°Cat760mmHg
• Flash Point: 181.9°C
• Density: 0.99g/cm³

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-(diphenylmethylidene)-1-phenylmethanamine

There total 30 articles about N-(diphenylmethylidene)-1-phenylmethanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

benzophenone (119-61-9) + N-benzyl-N,N-bis(trimethylsilyl)amine (18406-59-2) → benzhydrylidene-benzyl-amine (7699-79-8)

Guidance literature:

trimethylsilyl trifluoromethanesulfonate; In 1,2-dichloro-ethane; for 2h; Heating;

DOI:10.1246/cl.1985.1371

Reference yield: 95.0%

benzophenone (119-61-9) + benzylamine (100-46-9) → benzhydrylidene-benzyl-amine (7699-79-8)

Guidance literature:

With titanium(IV) isopropylate; In toluene; at 80 ℃; Inert atmosphere;

DOI:10.1021/acs.orglett.8b00778

Reference yield: 90.0%

methanol (67-56-1) + carbon dioxide (124-38-9,18923-20-1) + N-benzylidenediphenylmethanamine (62506-88-1) → benzhydrylidene-benzyl-amine (7699-79-8) + methyl Nα-(diphenylmethylene)-DL-phenylglycinate (171181-53-6)

Guidance literature:

carbon dioxide; N-benzylidenediphenylmethanamine; With 18-crown-6 ether; potassium tert-butylate; In tetrahydrofuran; at 25 ℃; for 18h; under 3750.38 Torr; Autoclave; Schlenk technique;

methanol; With diazomethyl-trimethyl-silane; In diethyl ether; hexane; Reagent/catalyst; Autoclave;

DOI:10.1002/chem.201604623

upstream raw materials:

pyridine

Dichlorodiphenylmethane

benzylamine

N-benzylidenediphenylmethanamine

Downstream raw materials:

N-Benzhydrylidene-1,2,N'-triphenyl-ethane-1,2-diamine

benzophenone

benzylamine

1-benzyl-2,2-diphenyl-3-fluoroaziridine

Refernces

• 1、 Cho, Eun Jin,Hwang, Ho Seong,Kang, Jihee,Soni, Vineet Kumar. "Direct C(sp3)-N Radical Coupling: Photocatalytic C-H Functionalization by Unconventional Intermolecular Hydrogen Atom Transfer to Aryl Radical". supporting information. . Retrieved 2020/08/12.
• 2、 Wang, Rui,Ma, Mengyue,Gong, Xu,Panetti, Grace B.,Fan, Xinyuan,Walsh, Patrick J.. "Visible-Light-Mediated Umpolung Reactivity of Imines: Ketimine Reductions with Cy2NMe and Water". supporting information. p. 2433 - 2436. Retrieved 2018/04/27.