Methyl 1-naphthoate

Base Information

Chemical Name:Methyl 1-naphthoate
CAS No.:2459-24-7
Molecular Formula:C12H10 O2
Molecular Weight:186.21
Hs Code.:2916399090
European Community (EC) Number:249-242-0,695-423-6
NSC Number:23049
DSSTox Substance ID:DTXSID901030976
Nikkaji Number:J47.355C
Wikidata:Q63408692
Mol file:2459-24-7.mol

Synonyms:Methyl 1-naphthoate;2459-24-7;1-Naphthoic Acid Methyl Ester;methyl naphthalene-1-carboxylate;1-Naphthalenecarboxylic acid, methyl ester;1-Naphthoic acid, methyl ester;Methyl 1-naphthalenecarboxylate;1-(Methoxycarbonyl)naphthalene;naphthalene-1-carboxylic acid methyl ester;1-Naphthalenecarboxylic acid methyl ester;Methyl naphthoate;EINECS 249-242-0;methyl alpha-naphthoate;28804-90-2;SCHEMBL522791;HMRROBKAACRWBP-UHFFFAOYSA-;DTXSID901030976;CAA45924;NSC23049;MFCD00094243;NSC-23049;AKOS008905557;CS-0138236;FT-0634297;N0615;D91749;EN300-341832;Q63408692;InChI=1/C12H10O2/c1-14-12(13)11-8-4-6-9-5-2-3-7-10(9)11/h2-8H,1H3

Suppliers and Price of Methyl 1-naphthoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
1-NaphthoicAcidMethylEster
2.5g
$ 90.00

TCI Chemical
Methyl 1-Naphthoate
25G
$ 60.00

Crysdot
Methyl 1-Naphthoate 97%
500g
$ 920.00

Chemenu
Methyl 1-Naphthoate 97%
500g
$ 868.00

Apolloscientific
1-Naphthoicacidmethylester 95%
25g
$ 312.00

Apolloscientific
1-Naphthoicacidmethylester 95%
5g
$ 145.00

American Custom Chemicals Corporation
1-NAPHTHOIC ACID METHYLESTER 95.00%
5MG
$ 502.24

Ambeed
Methyl 1-Naphthoate 95%
100g
$ 366.00

Ambeed
Methyl 1-Naphthoate 95%
5g
$ 33.00

Ambeed
Methyl 1-Naphthoate 95%
25g
$ 111.00

Total 12 raw suppliers

Chemical Property of Methyl 1-naphthoate

Chemical Property:

Melting Point:59.5°C
Refractive Index:1.6100 to 1.6140
Boiling Point:303.8°Cat760mmHg
Flash Point:145.8°C
PSA：26.30000
Density:1.153g/cm³
LogP:2.62640
Storage Temp.:Sealed in dry,Room Temperature
XLogP3:3.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:186.068079557
Heavy Atom Count:14
Complexity:212

Purity/Quality:

99%, ^*data from raw suppliers

1-NaphthoicAcidMethylEster ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 36/37/38
Safety Statements: 26-36/37/39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=CC=CC2=CC=CC=C21

Technology Process of Methyl 1-naphthoate

There total 12 articles about Methyl 1-naphthoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 941-98-0
1'-naphthacetophenone

: 75-25-2
Bromoform

: 2459-24-7
methyl 1-naphthoate

: 149-73-5
trimethyl orthoformate

Guidance literature:: With methanol; sodium bromide; at 30 ℃; electrolysis (Pt-anode, Cu-Zn (60:40)-cathode, 220 mA/cm² constant current density);
DOI:10.1016/S0040-4020(01)87078-2

Reference yield: 63.0%

: 201230-82-2
carbon monoxide

: 90-11-9
1-Bromonaphthalene

: 2459-24-7
methyl 1-naphthoate

: 86-55-5
1-naphthalenecarboxylic acid

Guidance literature:: With methanol; tert-Amyl alcohol; sodium hydride; cobalt(II) acetate; In tetrahydrofuran; at 40 ℃; for 83h; under 760 Torr; Irradiation;
DOI:10.1021/jo00131a005

Reference yield: 61.0%

: 67-56-1
methanol

: 90-11-9
1-Bromonaphthalene

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 2459-24-7
methyl 1-naphthoate

: 3815-24-5
N,N-dimethyl-1-naphthamide

Guidance literature:: 1-Bromonaphthalene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h;

N,N-dimethyl-formamide; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 2h;

methanol; Further stages;
DOI:10.1016/j.tet.2012.04.016