3-cyclohexylcyclohexene

Base Information

• Chemical Name: 3-cyclohexylcyclohexene
• CAS No.: 1808-09-9
• Molecular Formula: C12H20
• Molecular Weight: 164.291
• Mol file: 1808-09-9.mol

Synonyms:

Chemical Property of 3-cyclohexylcyclohexene

Chemical Property:

• Boiling Point: 230.4°Cat760mmHg
• Flash Point: 86.6°C
• Density: 0.913g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-cyclohexylcyclohexene

There total 16 articles about 3-cyclohexylcyclohexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

cyclohex-2-en-1-yl 2,4,6-trimethylbenzoate (102853-22-5) + cyclohexylmagnesium bromide (931-50-0) → 2-cyclohexyl-cyclohexene (1808-09-9)

Guidance literature:

With CuCN; In diethyl ether; for 4h; Ambient temperature;

DOI:10.1021/jo00365a006

Reference yield: 49.0%

methanol (67-56-1) + cyclohexene (110-83-8) → cyclohexylcyclohexane (92-51-3) + bicyclohexyl-2,2'-diene (1541-20-4) + 2-cyclohexyl-cyclohexene (1808-09-9) + cyclohexylmethyl alcohol (100-49-2)

Guidance literature:

With europium(III) chloride; In methanol; for 8h; Further byproducts given; Irradiation;

DOI:10.1246/bcsj.59.1195

Reference yield: 49.0%

methanol (67-56-1) + cyclohexene (110-83-8) → cyclohexylcyclohexane (92-51-3) + bicyclohexyl-2,2'-diene (1541-20-4) + 2-cyclohexyl-cyclohexene (1808-09-9) + 3-hydroxymethylcyclohexene (103668-33-3,3309-97-5) + cyclohexylmethyl alcohol (100-49-2)

Guidance literature:

With europium(III) chloride; for 8h; Product distribution; Mechanism; Irradiation; also other alkenes and reaction conditions;

DOI:10.1246/bcsj.59.1195

upstream raw materials:

1-bromocyclohex-1-ene

cyclohexylmagnesium bromide

rac-3-bromocyclohexene

6-cyclohexyl-1-(1-pyrrolidinyl)cyclohexene

Refernces

• 1、 Sun, Chun-Yi,To, Wai-Pong,Hung, Faan-Fung,Wang, Xin-Long,Su, Zhong-Min,Che, Chi-Ming. "Metal-organic framework composites with luminescent pincer platinum(II) complexes: 3MMLCT emission and photoinduced dehydrogenation catalysis". . p. 2357 - 2364. Retrieved 2018/03/05.
• 2、 Singaram, Bakthan,Rangaishenvi, Milind V.,Brown, Herbert C.,Goralski, Christian G.,Hasha, Dennis L.. "Hydroboration. 86. Convenient Conversion of Aldehydes and Ketones into the Corresponding Alkenes via Hydroboration of their Enamines. A Remarkably Simple Synthesis of Either (Z)- or (E)-Alkenes". . p. 1543 - 1549. Retrieved 2007/10/02.