Decanoic acid trimethylsilyl ester

Base Information

• Chemical Name: Decanoic acid trimethylsilyl ester
• CAS No.: 55494-15-0
• Molecular Formula: C13H28O2Si
• Molecular Weight: 244.45
• Mol file: 55494-15-0.mol

Synonyms:Decanoic acid,trimethylsilyl ester;

Chemical Property of Decanoic acid trimethylsilyl ester

Chemical Property:

• PSA: 26.30000
• LogP: 4.50520

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Decanoic acid trimethylsilyl ester

There total 4 articles about Decanoic acid trimethylsilyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

chloro-trimethyl-silane (75-77-4) + 1-decanoic acid (334-48-5) → decanoic acid trimethylsilyl ester (55494-15-0)

Guidance literature:

1-decanoic acid; With pyridine; In tetrahydrofuran; at 0 ℃; for 0.5h;

chloro-trimethyl-silane; With 1,1,1,3,3,3-hexamethyl-disilazane; In tetrahydrofuran; at 0 - 20 ℃; for 12h;

DOI:10.1016/j.tet.2007.01.026

Reference yield: 48.0%

1-decanoic acid (334-48-5) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) → decanoic acid trimethylsilyl ester (55494-15-0)

Guidance literature:

With iodine; In neat (no solvent); at 20 ℃; for 2h; Green chemistry;

DOI:10.1016/j.tet.2016.08.003

Reference yield:

chloro-trimethyl-silane (75-77-4) + 1-decanoic acid (334-48-5) + N,O-Bis(trimethylsilyl)trifluoroacetamide (25561-30-2) → C13H26O3Si + C16H34O3Si2 + decanoic acid trimethylsilyl ester (55494-15-0)

Guidance literature:

1-decanoic acid; With (S)-α-hydroxy acid oxidase from Aerococcus viridans; P₄₅₀ from Sphingomonas paucimobilis; dihydrogen peroxide; In ethanol; at 20 ℃; for 22h; pH=7.4; Enzymatic reaction;

chloro-trimethyl-silane; N,O-Bis(trimethylsilyl)trifluoroacetamide; With pyridine; at 20 ℃; for 2h; Reagent/catalyst;

DOI:10.1002/anie.201710227

upstream raw materials:

chloro-trimethyl-silane

1-decanoic acid

N,O-Bis(trimethylsilyl)trifluoroacetamide

1,1,1,3,3,3-hexamethyl-disilazane

Downstream raw materials:

Hexamethyldisiloxane

tert-butyl decanoate

{1-[1-Cyclohexyl-meth-(Z)-ylidene]-decyloxy}-trimethyl-silane

{1-[1-Cyclohexyl-meth-(Z)-ylidene]-decyloxy}-trimethyl-silane