azane, oxo-, bromide, oxide (1:1)

Base Information

• Chemical Name: azane, oxo-, bromide, oxide (1:1)
• CAS No.: 13536-70-4
• Molecular Formula: BrN O2
• Molecular Weight: 125.909
• Mol file: 13536-70-4.mol

Synonyms:Nitrylbromide (7CI,8CI)

Chemical Property of azane, oxo-, bromide, oxide (1:1)

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 45.82000
• Density: g/cm³
• LogP: 1.09620

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of azane, oxo-, bromide, oxide (1:1)

There total 4 articles about azane, oxo-, bromide, oxide (1:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bromine (7726-95-6) + nitrogen(II) oxide (10102-43-9) + dinitrogen pentoxide (10102-03-1) → nitryl bromide (13536-70-4) + nitric acid (7697-37-2,78989-43-2) + Nitrogen dioxide (10102-44-0)

Guidance literature:

In gas; N2O5 in a He stream (1 atm) was reacted with BrNO, formed from Br2 and NO, at 298 K for 5 - 30 min; detected by IR;

DOI:10.1021/j100348a005

Reference yield:

Nitrogen dioxide (10102-44-0) + nitrosyl bromide (13444-87-6) → nitryl bromide (13536-70-4) + nitrogen(II) oxide (10102-43-9)

Guidance literature:

In neat (no solvent); rapid introducing BrNO into 3 mbar NO2 (total pressure 6 mbar); not isolated, equilibrium position detd. by IR spectroscopy;

DOI:10.1021/ic9803006

Reference yield:

dinitrogen pentoxide (10102-03-1) + sodium bromide (7647-15-6) → nitryl bromide (13536-70-4) + nitric acid (7697-37-2,78989-43-2)

Guidance literature:

In gas; N2O5 in a He stream (1 atm) was reacted with solid NaBr at 298 K for 5 - 30 min; detected by IR;

DOI:10.1021/j100348a005

upstream raw materials:

potassium nitrite

bromine

nitrogen(II) oxide

dinitrogen pentoxide

Downstream raw materials:

bromine

Nitrogen dioxide

potassium nitrite

bromine chloride