ethyl phenyl carbonate

Base Information

• Chemical Name: ethyl phenyl carbonate
• CAS No.: 3878-46-4
• Molecular Formula: C9H10O3
• Molecular Weight: 166.177
• Hs Code.: 2920909090
• Mol file: 3878-46-4.mol

Synonyms:carbonic acid ethyl ester-phenyl ester;phenyl ethyl carbonate;Carbonic acid,ethyl phenyl ester;Kohlensaeure-aethylester-phenylester;Aethyl-phenyl-carbonat;Kohlensaeure-aethyl-phenyl-ester;

Chemical Property of ethyl phenyl carbonate

Chemical Property:

• Vapor Pressure: 0.0461mmHg at 25°C
• Boiling Point: 236.9°Cat760mmHg
• Flash Point: 99.4°C
• PSA: 35.53000
• Density: 1.108g/cm³
• LogP: 2.22190

Purity/Quality:

ETHYLPHENYL CARBONATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ethyl phenyl carbonate

There total 40 articles about ethyl phenyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

chloroformic acid ethyl ester (541-41-3) + phenol (108-95-2,27073-41-2) → ethyl phenyl carbonate (3878-46-4)

Guidance literature:

With pyridine; In toluene; at 220 ℃; for 24h;

Reference yield: 99.0%

diethyl dicarbonate (1609-47-8) + phenol (108-95-2,27073-41-2) → ethyl phenyl carbonate (3878-46-4)

Guidance literature:

With magnesium(II) perchlorate; at 40 ℃; for 5h;

DOI:10.1002/ejoc.200600366

Reference yield: 84.0%

chloroformic acid ethyl ester (541-41-3) + phenylmagnesium bromide → benzoic acid ethyl ester (93-89-0,99341-95-4) + ethyl phenyl carbonate (3878-46-4)

Guidance literature:

With copper(I) bromide; lithium bromide; In tetrahydrofuran; at 20 ℃;

DOI:10.1055/s-2007-973861

upstream raw materials:

bis(phenyl) carbonate

diethyl ether

ethanol

sodium ethanolate

Downstream raw materials:

N-Ethoxycarbonylpiperidine

phenol

ethanol

carbon dioxide

Refernces

• 1、 -. "ANALGESIC AND ANTI-ADDICTIVE COMPOSITIONS FOR TREATMENT OF CHRONIC PAIN AND OPIOID ADDICTION". Page/Page column 28; 29. . Retrieved 2020/06/10.
• 2、 Um, Ik-Hwan,Seo, Ji-Yoon,Kang, Ji-Sun,An, Jun-Sung. "A kinetic study on nucleophilic displacement reactions of phenyl Y-substituted-phenyl carbonates with alkali metal ethoxides: Metal ion effect and reaction mechanism". . p. 1007 - 1013,7. Retrieved 2020/08/24.