(Dichloromethyl)trimethylsilane

Base Information

• Chemical Name: (Dichloromethyl)trimethylsilane
• CAS No.: 5926-38-5
• Molecular Formula: C4H10Cl2Si
• Molecular Weight: 157.115
• European Community (EC) Number: 227-658-3
• NSC Number: 92687
• UNII: 8GQP7DV48U
• DSSTox Substance ID: DTXSID8064062
• Nikkaji Number: J47.897K
• Wikidata: Q63395864
• Mol file: 5926-38-5.mol

Synonyms:(Dichloromethyl)trimethylsilane;5926-38-5;Dichloromethyltrimethylsilane;dichloromethyl(trimethyl)silane;Silane, (dichloromethyl)trimethyl-;8GQP7DV48U;dichloromethyl-trimethyl-silane;EINECS 227-658-3;NSC 92687;NSC-92687;NSC92687;UNII-8GQP7DV48U;(Trimethylsilyl)dichloromethane;(dichloromethyl) trimethylsilane;SCHEMBL4731857;DTXSID8064062;MFCD00051448;(Dichloromethyl)trimethylsilane, 96%;AKOS015915813;FT-0604906;Q63395864

Chemical Property of (Dichloromethyl)trimethylsilane

Chemical Property:

• Vapor Pressure: 9.31mmHg at 25°C
• Refractive Index: n20/D 1.4455(lit.)
• Boiling Point: 136 °C at 760 mmHg
• Flash Point: 37.2 °C
• Density: 1.023 g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 155.9928822
• Heavy Atom Count: 7
• Complexity: 55.2

Purity/Quality:

98%,99%, ^*data from raw suppliers

(Dichloromethyl)trimethylsilane 96% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R10:Flammable.; R36/37/38:Irritating to eyes, respiratory system and skin.
• Hazard Codes: R10:Flammable.; R36/37/38:Irritating to eyes, respiratory system and skin.
• Statements: 10
• Safety Statements: 16

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C[Si](C)(C)C(Cl)Cl

Technology Process of (Dichloromethyl)trimethylsilane

There total 15 articles about (Dichloromethyl)trimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

dichloromethyldimethylsilyl chloride (18171-59-0) → (dichloromethyl)trimethylsilane (5926-38-5)

Guidance literature:

With CH₃MgBr; In not given;

DOI:10.1021/ja01184a032

Reference yield: 46.0%

chlorine (7782-50-5) + Chloromethyltrimethylsilane (2344-80-1) → (dichloromethyl)trimethylsilane (5926-38-5) + bis(chloromethyl)dimethylsilane (2917-46-6)

Guidance literature:

In neat (no solvent); Irradiation (UV/VIS); irradiation of (CH3)3Si(CH2Cl) and gaseous Cl2 at temp. of boiling xylene;;

DOI:10.1021/ja01148a542

Reference yield: 31.0%

chloro-trimethyl-silane (75-77-4) + chloroform (67-66-3,8013-54-5) → (dichloromethyl)trimethylsilane (5926-38-5) + trichloromethyltrimethylsilane (5936-98-1)

Guidance literature:

With tetrahydrofuran; magnesium; In hexane; for 4h; Heating;

upstream raw materials:

diethyl ether

dichloromethyldimethylsilyl chloride

methylmagnesium bromide

Chloromethyltrimethylsilane

Downstream raw materials:

dichloromethane

dimethylsilicon dichloride

formaldehyd

bis(trimethylsilyl)dichloromethane