Dimethylnitramine

Base Information

• Chemical Name: Dimethylnitramine
• CAS No.: 4164-28-7
• Molecular Formula: C2H6N2O2
• Molecular Weight: 90.0818
• Hs Code.: 2928000090
• NSC Number: 137860
• UNII: K999F18G9O
• DSSTox Substance ID: DTXSID6020519
• Wikidata: Q27282123
• ChEMBL ID: CHEMBL406511
• Mol file: 4164-28-7.mol

Synonyms:dimethylnitramine;N-nitrodimethylamine

Chemical Property of Dimethylnitramine

Chemical Property:

• Vapor Pressure: 0.887mmHg at 25°C
• Melting Point: 58°C
• Refractive Index: 1.4462 (estimate)
• Boiling Point: 187°C at 760 mmHg
• PKA: -7.12±0.70(Predicted)
• Flash Point: 63.7°C
• PSA: 49.06000
• Density: 1.104g/cm³
• LogP: 0.26290
• XLogP3: 0.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 90.042927438
• Heavy Atom Count: 6
• Complexity: 55.1

Purity/Quality:

99% ^*data from raw suppliers

DIMETHYL(NITRO)AMINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C)[N+](=O)[O-]

Technology Process of Dimethylnitramine

There total 18 articles about Dimethylnitramine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 12.0%

N,N,N,N,N,N-hexamethylphosphoric triamide (680-31-9) → N-Nitrosodimethylamine (62-75-9) + N-nitrodimethylamine (4164-28-7)

Guidance literature:

With nitric acid; for 1.5h; Ambient temperature;

DOI:10.1021/jo00252a058

Reference yield:

N-Nitrosodimethylamine (62-75-9) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + N-nitrodimethylamine (4164-28-7)

Guidance literature:

meso-tetraphenylporphyrin iron(III) chloride; In benzene; for 3h; Product distribution; oxidation with iodosylbenzene, or 3-chloroperoxybenzoic acid, or t-butylhydroperoxide;

Reference yield:

N,N-Dimethylhydrazine (57-14-7) → 1,3-oxazolidine (504-76-7) + N-Methylformamide (123-39-7) + butanedial (638-37-9) + N,N-Dimethylamino acetonitrile (926-64-7) + N-methyl-N-(methyleneamino)methanamine (2035-89-4) + N-Nitrosodimethylamine (62-75-9) + N-nitrodimethylamine (4164-28-7) + dimethyl amine (124-40-3)

Guidance literature:

With α-manganese oxide; water; at 0 ℃; Reagent/catalyst; UV-irradiation; Flow reactor;

DOI:10.1039/d0nj05167e

upstream raw materials:

diazomethane

N,N,N,N,N,N-hexamethylphosphoric triamide

N-Nitrosodimethylamine

Tetramethyltetrazon

Downstream raw materials:

formaldehyd

methylamine

formic acid

dimethyl amine

Refernces

• 1、 Ruomeng, Hou,Ying, Jia,Yuanzheng, Huang,Keke, Shen,Huixin, Zhu. "TiO2-reduced graphene oxide for the removal of gas-phase unsymmetrical dimethylhydrazine". . p. 394 - 402. Retrieved 2021/01/11.
• 2、 Matsunaga, Hiroki,Katoh, Katsumi,Habu, Hiroto,Noda, Masaru,Miyake, Atsumi. "Thermal behavior of ammonium dinitramide and amine nitrate mixtures". . p. 2677 - 2685. Retrieved 2018/11/23.