BENZYLOXYTRIMETHYLSILANE

Base Information

• Chemical Name: BENZYLOXYTRIMETHYLSILANE
• CAS No.: 14642-79-6
• Molecular Formula: C10H16OSi
• Molecular Weight: 180.322
• Hs Code.: 29310099
• Mol file: 14642-79-6.mol

Synonyms:Silane,(benzyloxy)trimethyl- (6CI,7CI,8CI);Silane, trimethyl(phenylmethoxy)- (9CI);(Benzyloxy)trimethylsilane;Benzyl alcohol trimethylsilyl ether;Benzyltrimethylsilyl ether;Phenyl(trimethylsiloxy)methane;Trimethyl(benzyloxy)silane;Trimethyl(phenylmethoxy)silane;

Chemical Property of BENZYLOXYTRIMETHYLSILANE

Chemical Property:

• Appearance/Colour: Clear very pale yellow liquid
• Vapor Pressure: 0.373mmHg at 25°C
• Refractive Index: 1.4770
• Boiling Point: 204.6 °C at 760 mmHg
• Flash Point: 73.9 °C
• PSA: 9.23000
• Density: 0.913 g/cm³
• LogP: 3.03810
• Solubility.: Chloroform, Dichloromethane

Purity/Quality:

97% ^*data from raw suppliers

Benzyloxytrimethylsilane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R36/37/38:
• Hazard Codes: R36/37/38:
• Statements: 36/37/38
• Safety Statements: 26-36/37/39-24/25-23

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Benzyloxytrimethylsilane is an intermediate in the synthesis of [Di(benzyloxy)methyl]benzene (D417965), which is a reagent in organic chemical synthesis such as the synthesis of O-benzyl protected anti aldols.

Technology Process of BENZYLOXYTRIMETHYLSILANE

There total 68 articles about BENZYLOXYTRIMETHYLSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) + benzyl alcohol (100-51-6,185532-71-2) → benzyloxy-trimethylsilane (14642-79-6)

Guidance literature:

With meso-tetrakis(tetraphenyl)porphyrin iron(III) chloride; In acetonitrile; Ambient temperature;

DOI:10.1080/00397919708004140

Reference yield: 99.0%

trimethylsilylazide (4648-54-8) + benzyl alcohol (100-51-6,185532-71-2) → benzyloxy-trimethylsilane (14642-79-6)

Guidance literature:

tetrabutylammomium bromide; at 30 ℃; for 0.00333333h;

DOI:10.1021/jo015814s

Reference yield: 98.0%

chloro-trimethyl-silane (75-77-4) + benzyl alcohol (100-51-6,185532-71-2) → benzyloxy-trimethylsilane (14642-79-6)

Guidance literature:

With iron perchlorate hexahydrate; In dichloromethane; at 20 ℃; for 0.416667h;

DOI:10.1080/10426500802336606

upstream raw materials:

chloro-trimethyl-silane

benzyl alcohol

1,1,1,3,3,3-hexamethyl-disilazane

Hexamethyldisiloxane

Downstream raw materials:

α-trimethylsilyl-α-trimethylsiloxytoluene

α-Triaethylsiloxy-α-trimethylsilyltoluol

Benzyl-methansulfinat

Benzyl-(toluol-α-sulfinat)

Refernces

• 1、 Wang, De-Kun,Zhou, Yong-Gui,Tang, Yong,Hou, Xue-Long,Dai, Li-Xin. "Allylation of imines with allyltrimethylsilane and experimental evidences for a fluoride-triggered autocatalysis mechanism of the Sakurai- Hosomi reaction". . p. 4233 - 4237. Retrieved 1999.
• 2、 Yao, Hongyan,Wang, Yongsheng,Razi, Maryam Kargar. "An asymmetric Salamo-based Zn complex supported on Fe3O4MNPs: a novel heterogeneous nanocatalyst for the silyl protection and deprotection of alcohols under mild conditions". . p. 12614 - 12625. Retrieved 2021/04/14.
• 3、 -. "Use of Silylated Formiates as Hydrosilane Equivalents". Paragraph 0502-0505. . Retrieved 2021/09/26.