PLATINUM NANOCAGE

Base Information

• Chemical Name: PLATINUM NANOCAGE
• CAS No.: 262354-73-4
• Molecular Formula: C₈₄H₉₆N₃₆Pt₆*12NO₃
• Molecular Weight: 3524.47
• Mol file: 262354-73-4.mol

Synonyms:PLATINUM NANOCAGE

Chemical Property of PLATINUM NANOCAGE

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

PLATINUM-NANOCAGE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of PLATINUM NANOCAGE

There total 3 articles about PLATINUM NANOCAGE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

2,4,6-tri(4-pyridyl)-1,3,5-triazine (42333-78-8) + ethylenediamine platinum(II) nitrate (50475-22-4) → Pt6(ethylenediamine)6(2,4,6-tris-4-pyridyl-1,3,5-triazine)4(NO3)12 (262354-73-4)

Guidance literature:

In water; at 150 ℃; for 72h; Sealed tube;

DOI:10.1002/chem.201603017

Reference yield:

1,4-pyrazine (290-37-9) + 2,4,6-tri(4-pyridyl)-1,3,5-triazine (42333-78-8) + ethylenediamine platinum(II) nitrate (50475-22-4) → Pt6(ethylenediamine)6(2,4,6-tris-4-pyridyl-1,3,5-triazine)4(NO3)12 (262354-73-4) + Pt4(ethylenediamine)4(pyrazine)4(NO3)8

Guidance literature:

In water-d2; heating of mixt. for several days; detd. by NMR;

DOI:10.1002/anie.200351797

Reference yield:

C84H96N36Pt6(12+)*12NO3(1-)*4C15H27Cl2N3O6Pt → cisplatin (15663-27-1) + Pt6(ethylenediamine)6(2,4,6-tris-4-pyridyl-1,3,5-triazine)4(NO3)12 (262354-73-4) + succinic acid (110-15-6) + 1-Adamantanamine (768-94-5)

Guidance literature:

With ascorbic acid; at 37 ℃; for 24h;

DOI:10.1039/c4sc01892c

upstream raw materials:

1,4-pyrazine

2,4,6-tri(4-pyridyl)-1,3,5-triazine

ethylenediamine platinum(II) nitrate

Refernces

• 1、 Leenders, Stefan H. A. M.,Becker, René,Kumpulainen, Tatu,de Bruin, Bas,Sawada, Tomohisa,Kato, Taito,Fujita, Makoto,Reek, Joost N. H.. "Selective Co-Encapsulation Inside an M6L4Cage". supporting information. p. 15468 - 15474. Retrieved 2016/10/13.