bis(4-methoxyphenyl)methyl trimethylsilyl ether

Base Information

• Chemical Name: bis(4-methoxyphenyl)methyl trimethylsilyl ether
• CAS No.: 174968-73-1
• Molecular Formula: C₁₈H₂₄O₃Si
• Molecular Weight: 316.472
• Mol file: 174968-73-1.mol

Synonyms:bis(4-methoxyphenyl)methyl trimethylsilyl ether

Chemical Property of bis(4-methoxyphenyl)methyl trimethylsilyl ether

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(4-methoxyphenyl)methyl trimethylsilyl ether

There total 3 articles about bis(4-methoxyphenyl)methyl trimethylsilyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

chloro-trimethyl-silane (75-77-4) + 4,4'-Dimethoxybenzhydrol (728-87-0) → bis(4-methoxyphenyl)methyl trimethylsilyl ether (174968-73-1)

Guidance literature:

With triethylamine; In benzene; at 20 ℃; for 7h;

DOI:10.1021/jo0015927

Reference yield: 74.0%

chloro-trimethyl-silane (75-77-4) + ethyl trifluoroacetate, (383-63-1) + bis(p-methoxyphenyl)methanone (90-96-0) → 2-ethoxy-1,1,1-trifluoro-3,3-bis(4'-methoxyphenyl)-2,3-bistrimethylsiloxypropane (1187875-59-7) + bis(4-methoxyphenyl)methyl trimethylsilyl ether (174968-73-1)

Guidance literature:

With magnesium; In 1-methyl-pyrrolidin-2-one; at 20 ℃; Inert atmosphere;

DOI:10.1016/j.tetlet.2009.11.110

Reference yield: 38.0%

1-bromo-4-methoxy-benzene (104-92-7) + 4-methoxy-benzaldehyde (123-11-5) + 2,3,5,6-tetramethyl-1,4-bis(trimethylsilyl)-1,4-diaza-2,5-cyclo-hexadiene (78279-92-2) → bis(4-methoxyphenyl)methyl trimethylsilyl ether (174968-73-1)

Guidance literature:

With Ni(acetylacetate)2; In toluene; at 80 ℃; for 18h;

DOI:10.1002/anie.201507902

upstream raw materials:

chloro-trimethyl-silane

4,4'-Dimethoxybenzhydrol

ethyl trifluoroacetate,

bis(p-methoxyphenyl)methanone

Downstream raw materials:

1,5-bis[bis(4-methoxyphenyl)methyl]-2,4-dimethoxybenzene

Hexamethyldisiloxane

diether

bis(p-methoxyphenyl)methanone