[pyridinium][(rccc-2,8,14,20-tetrakis-(iso-butyl)-phosphonito cavitant)Cu4(mu-Cl)4(μ4-Cl)]CH3CNCH2Cl2

Base Information

Chemical Name:[pyridinium][(rccc-2,8,14,20-tetrakis-(iso-butyl)-phosphonito cavitant)Cu4(mu-Cl)4(μ4-Cl)]*CH3CN*CH2Cl2
CAS No.:855304-15-3
Molecular Formula:CH₂Cl₂*C₂H₃N*C₅H₆N*C₆₈H₆₈Cl₅Cu₄O₈P₄
Molecular Weight:1774.72
Hs Code.:

Synonyms:

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Chemical Property of [pyridinium][(rccc-2,8,14,20-tetrakis-(iso-butyl)-phosphonito cavitant)Cu4(mu-Cl)4(μ4-Cl)]*CH3CN*CH2Cl2

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Technology Process of [pyridinium][(rccc-2,8,14,20-tetrakis-(iso-butyl)-phosphonito cavitant)Cu4(mu-Cl)4(μ4-Cl)]*CH3CN*CH2Cl2

There total 1 articles about [pyridinium][(rccc-2,8,14,20-tetrakis-(iso-butyl)-phosphonito cavitant)Cu4(mu-Cl)4(μ4-Cl)]*CH3CN*CH2Cl2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 110-86-1
pyridine

: 75-09-2
dichloromethane

: 635753-30-9
rccc-2,8,14,20-tetrakis-(iso-butyl)-phosphonito cavitant

: 75-05-8,26809-02-9
acetonitrile

: copper(l) chloride

: 855304-15-3
[pyridinium][(rccc-2,8,14,20-tetrakis-(iso-butyl)-phosphonito cavitant)Cu4(mu-Cl)4(μ4-Cl)]*CH3CN*CH2Cl2

Guidance literature:: In dichloromethane; under N2 atm. using Schlenk techniques; mixt. of excess CuCl, phosphonitocavitand, pyridine in CH2Cl2 was stirred at room temp. overnight; soln. filtered; solvent was pumped off; residue recrystd. (CH2Cl2/MeOH);elem. anal.;
DOI:10.1016/j.molstruc.2005.02.002

Reference yield: 76.0%

: 67-56-1
methanol

: 855304-15-3
[pyridinium][(rccc-2,8,14,20-tetrakis-(iso-butyl)-phosphonito cavitant)Cu4(mu-Cl)4(μ4-Cl)]*CH3CN*CH2Cl2

: 7647-15-6
sodium bromide

: 855310-92-8
[pyridinium][(rccc-2,8,14,20-tetrakis-(iso-butyl)-phosphonito cavitant)Cu4(mu-Cl)4(μ4-Br)]*CH3OH

Guidance literature:: In tetrahydrofuran; water; under N2 atm. using Schlenk techniques; to soln. of Cu complex in THF added soln. of NaBr in water; mixt. stirred for 2 h; solvent was pumped off; residue washed (MeOH, Et2O); recrystd. (CH2Cl2/MeOH); elem. anal.;
DOI:10.1016/j.molstruc.2005.02.002

Reference yield: 72.0%

: 67-56-1
methanol

: 855304-15-3
[pyridinium][(rccc-2,8,14,20-tetrakis-(iso-butyl)-phosphonito cavitant)Cu4(mu-Cl)4(μ4-Cl)]*CH3CN*CH2Cl2

: 7681-82-5,24359-64-6,41927-88-2,115813-40-6
sodium iodide

: 855310-94-0
[pyridinium][(rccc-2,8,14,20-tetrakis-(iso-butyl)-phosphonito cavitant)Cu4(mu-Cl)4(μ4-I)]*CH3OH

Guidance literature:: In tetrahydrofuran; water; under N2 atm. using Schlenk techniques; to soln. of Cu complex in THF added soln. of NaI in water; mixt. stirred for 2 h; solvent was pumped off; residue washed (MeOH, Et2O); recrystd. (CH2Cl2/MeOH); elem. anal.;
DOI:10.1016/j.molstruc.2005.02.002