Chloro(dimethyl)stannane

Base Information

Chemical Name:Chloro(dimethyl)stannane
CAS No.:16561-41-4
Molecular Formula:C2H7ClSn
Molecular Weight:185.241
Hs Code.:
DSSTox Substance ID:DTXSID30194042,DTXSID10275409
Mol file:16561-41-4.mol

Synonyms:Stannyl, chlorodimethyl-;DIMETHYLTIN CHLORIDE;41079-92-9;chloro(dimethyl)stannane;Dimethylzinnchlorid;SCHEMBL358071;SCHEMBL358072;DTXSID10275409;DTXSID30194042;16561-41-4

Suppliers and Price of Chloro(dimethyl)stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of Chloro(dimethyl)stannane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:184.918005
Heavy Atom Count:4
Complexity:13.5

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Sn](C)Cl

Technology Process of Chloro(dimethyl)stannane

There total 2 articles about Chloro(dimethyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 753-73-1
dimethyltin dichloride

: 16393-88-7
trimethyl(trimethylstannyl)silane

: 993-07-7
trimethylsilan

: 1066-45-1
trimethyltin(IV)chloride

: 594-27-4
tetramethylstannane

: 58529-40-1
1,2-dichloro-tetramethyl-distannane

: 16561-41-4
dimethyltin chloride

Guidance literature:: With methanol; In methanol; byproducts: Me3SiCl, Me3SiOSiMe3; a mixt. of Me3SiSnMe3 and Me2SiCl2 in methanol was kept for 150 min, reaction was followed by (1)H NMR spectroscopy; 70% of the substrate had been consumed, rate const. is given; not isolated, identified by (1)H NMR spectrum; Kinetics;
DOI:10.1016/0022-328X(85)80065-6

Reference yield:

: 993-07-7
trimethylsilan

: 753-73-1
dimethyltin dichloride

: 75-77-4
chloro-trimethyl-silane

: 16561-41-4
dimethyltin chloride

Guidance literature:: In methanol; initially Me3SiCl and Me2SnHCl are formed in an equil. process, but this is perturbed by the solvolysis of Me3SiCl and destruction of Me2SnHCl (this can be prevented by maintaining the system at low temp.), no evidence of Me3SiSiMe3 formation observed; (1)H NMR data;
DOI:10.1016/0022-328X(85)80065-6

Reference yield: 37.0%

: 36854-27-0,41366-87-4,32892-18-5
2,3-diphenylacrylic acid methyl ester

: 16561-41-4
dimethyltin chloride

: 95798-76-8
(CH₃)2ClSnCH(C₆H₅)CH(C₆H₅)COOCH₃

: threo-Me₂ClSnCH(Ph)CH(Ph)CO₂Me

Guidance literature:: With 2,2'-azobis(isobutyronitrile); In neat (no solvent); ratio Me2ClSnH : olefin = 2:1, stirred for 2580 min at room temp. underN2; column chromy. on silica gel, elem. anal.;
DOI:10.1021/om00125a013