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Conditions | Yield |
---|---|
With dihydrogen peroxide; bromine In dichloromethane; water at 20℃; for 2h; | 99% |
With water; potassium iodide at 20℃; for 3h; Electrochemical reaction; Green chemistry; | 72% |
With calcium dichloride dihydrate; oxone; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; water In dichloromethane at 20℃; for 4h; | 72% |
Conditions | Yield |
---|---|
With [{(PhN)MeC(Nt-Bu)}AlMe(μ-OMe)]2 at 20℃; for 0.5h; Tishchenko-Claisen Dismutation; Inert atmosphere; Schlenk technique; Green chemistry; | 99% |
With aluminium propanolate | |
With Mg-tetrakis(methoxy)borate; mercury dichloride In diethyl ether | |
With Rh(PhBP3)(H)2(NCMe) In benzene-d6 at 20℃; for 0.0166667h; Tishchenko reaction; Inert atmosphere; |
Conditions | Yield |
---|---|
With Dowex 50Wx2 hydrogen form resin at 108 - 113℃; Reagent/catalyst; Autoclave; Large scale; | 97.36% |
With salicylic acid resin supported FeCl3 In benzene at 125℃; for 2.11667h; | 95.8% |
With Rhizomucor miehei lipase In n-heptane at 40℃; for 24h; Enzymatic reaction; | 95.3% |
(PPh3)3CoH(N2)
phenyl propionate
A
HCo(CO)(P(C6H5)3)3
B
propyl propionate
C
phenoxotris(triphenylphosphine)cobalt(I)
D
ethane
E
nitrogen
Conditions | Yield |
---|---|
In toluene byproducts: H2; EtCO2Ph added to CoH(N2)(PPh3)3 in toluene in vac., reacted for 3 days at room temp.; liquid phase analysed by GLC; hexane added, ppt. filtered, washed with hexane, dried in vac., recrystd. from C6H6-hexane; | A n/a B 33% C 62% D 23% E 85% |
(PPh3)3CoH(N2)
propionic acid anhydride
A
Co(1+)*C2H5CO2(1-)=Co(OCOC2H5)
B
propyl propionate
C
ethane
D
nitrogen
E
hydrogen
Conditions | Yield |
---|---|
In toluene in toluene at room temp. for 1 day; | A n/a B 28% C 26% D 84% E 15% |
normal propyl hypochlorite
propyl propionate
Conditions | Yield |
---|---|
In tetrachloromethane for 4h; Irradiation; | 75% |
In benzene Ambient temperature; Irradiation; | 75% |
trimethylsilyl propionate
propyl propionate
Conditions | Yield |
---|---|
With hydrogen; chromium(III) oxide; nickel(III) oxide |
Conditions | Yield |
---|---|
With triphenylstannane |
Conditions | Yield |
---|---|
With dodecacarbonyl-triangulo-triruthenium; diphenyl acetylene at 145℃; for 4h; Product distribution; Mechanism; other alcohols; other reagents; var. time; | |
With [Ru(1,2-bis(diphenylphosphino)benzene )(CO)2Cl2]; potassium tert-butylate; acetone In toluene at 100℃; for 6h; | A 68 %Chromat. B 8 %Chromat. |
With [Ru(1,2-bis(diphenylphosphino)benzene )(CO)2Cl2]; potassium tert-butylate; acetone In toluene at 100℃; for 6h; | A 29 %Chromat. B 62 %Chromat. |
tert-Butyl peroxybenzoate
aluminium propanolate
A
propan-1-ol
B
propyl propionate
C
propyl benzoate
D
tert-butyl alcohol
Conditions | Yield |
---|---|
In benzene at 20℃; for 336h; Product distribution; Mechanism; other temperature and time; | |
20 deg C, 3 d, then 70 deg C, 30 h; Yield given. Yields of byproduct given; |
Molecular Structure:
Molecular Formula: C6H12O2
Molecular Weight: 116.1583
IUPAC Name: Propyl propanoate
Synonyms of Propyl propionate (CAS NO.106-36-5): 4-02-00-00707 (Beilstein Handbook Reference) ; AI3-24357 ; BRN 1699993 ; EINECS 203-389-7 ; FEMA No. 2958 ; NSC 72022 ; Propanoic acid, propyl ester ; Propionic acid, propyl ester ; Propyl propanoate ; Propyl propionate (natural) ; Propylester kyseliny propionove ; Propylester kyseliny propionove [Czech] ; n-Propyl propanoate ; n-Propyl propionate
CAS NO: 106-36-5
Classification Code: Skin / Eye Irritant
Melting point: −76 °C
Index of Refraction: 1.397
Molar Refractivity: 31.62 cm3
Molar Volume: 131 cm3
Surface Tension: 25.8 dyne/cm
Density: 0.886 g/cm3
Flash Point: 19.4 °C
Enthalpy of Vaporization: 35.54 kJ/mol
Boiling Point: 121.9 °C at 760 mmHg
Vapour Pressure: 14.3 mmHg at 25°C
Propyl propionate (CAS NO.106-36-5) is used in the coating printing ink profession one fine resolver.
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mammal (species unspecified) | LC50 | inhalation | 16900mg/m3 (16900mg/m3) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 51(5), Pg. 61, 1986. | |
mouse | LC50 | inhalation | 24gm/m3/2H (24000mg/m3) | "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 104, 1982. | |
rabbit | LD50 | oral | 3950mg/kg (3950mg/kg) | Industrial Medicine and Surgery. Vol. 41, Pg. 31, 1972. | |
rabbit | LD50 | skin | > 14128mg/kg (14128mg/kg) | Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 1, Pg. 177, 1992. | |
rat | LD50 | oral | 10331mg/kg (10331mg/kg) | SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" | Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 1, Pg. |
Reported in EPA TSCA Inventory.
Hazard Codes of Propyl propionate (CAS NO.106-36-5): Xn
Risk Statements: 10-20
R10: Flammable.
R20: Harmful by inhalation.
Safety Statements: 24
S24: Avoid contact with skin.
RIDADR: UN 3272 3/PG 2
WGK Germany: 1
RTECS: UF7100000
HazardClass: 3
PackingGroup: II
Moderately toxic by ingestion. Very mildly toxic by inhalation. A skin irritant. Combustible when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.