There are various hypervalent iodine compounds, such as the iodosylbenzene and diaryliodonium salts, which have been used for arene fluorination. These compounds can be versatile reagents for introducing fluorine atoms into arenes. The reaction mechanisms can vary, but they often involve oxidative addition of the C-F bond of the hypervalent iodine compound to the arene.
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1-fluoro-4,5-dimethoxy-2-methylbenzene
1-[2,4,6-trimethylphenylethynyl]-1,2-benziodoxol-3(1H)-one
Acetic acid (2R,3R,4S,5R,6R)-2-acetylamino-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester
N-(p-tolyl)-5,6-dihydro-4H-1,3-oxazin-2-amine
Ethanone, 1-(3-bromophenyl)-2-(diethylamino)-
2,3-bis((benzyloxy)methyl)oxirane
